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Key Documents

385395

Sigma-Aldrich

Acetaldeide dimetil acetale

95%

Sinonimo/i:

1,1-dimetossietano, Dimetil acetale

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About This Item

Formula condensata:
CH3CH(OCH3)2
Numero CAS:
Peso molecolare:
90.12
Beilstein:
1697039
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
eCl@ss:
39021102
ID PubChem:
NACRES:
NA.22

Densità del vapore

3.1 (vs air)

Livello qualitativo

Saggio

95%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.367 (lit.)

P. eboll.

64 °C (lit.)

Densità

0.852 g/mL at 25 °C (lit.)

Stringa SMILE

COC(C)OC

InChI

1S/C4H10O2/c1-4(5-2)6-3/h4H,1-3H3
SPEUIVXLLWOEMJ-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Kinetics of oxidative degradation of acetaldehyde dimethyl acetal has been studied by pulse radiolysis. It also undergoes addition with various ketones, esters, amides and thioesters in the presence of silyl trifluoromethanesulfonates and an amine base. Lewis acid-mediated reaction of the titanium enolate of (S)-N-acetyl-4-isopropyl-1,3-thiazolidine-2-thione with acetaldehyde dimethyl acetal has been studied.

Applicazioni

Acetaldehyde dimethyl acetal may be used in the preparation of glucoside derivatives of steganol. It may be used as polymer solvent for the encapsulation of water-soluble model protein, bovine serum albumin into biodegradable poly(D,L-lactic acid.

Pittogrammi

Flame

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

1.4 °F - closed cup

Punto d’infiammabilità (°C)

-17 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


Certificati d'analisi (COA)

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Enantiopure β-methoxy carboxyl derivatives from a chiral titanium enolate and dimethyl acetals.
Cosp A, et al.
Tetrahedron Letters, 42(28), 4629-4631 (2001)
R P Hicks et al.
Journal of natural products, 48(3), 357-362 (1985-05-01)
Glucoside derivatives of steganol analogous to the semisynthetic podophyllotoxin derivative, VP 16-213, were prepared. Glucosidation of steganol with 2, 3, 4, 6-tetra-O-benzylglucopyranose gave the alpha-anomer of the glucoside as the major product. Subsequent removal of the benzyl groups and reaction
B Gander et al.
Journal of microencapsulation, 12(1), 83-97 (1995-01-01)
The aim was to study the effect of the type of polymer solvent on characteristics of microspheres produced by spray drying. The water-soluble model protein, bovine serum albumin (BSA) was microencapsulated into biodegradable poly(D,L-lactic acid) using the following 10 different
M M Wiest et al.
Prostaglandins, leukotrienes, and essential fatty acids, 80(4), 221-227 (2009-03-25)
Increasing evidence is mounting in support of fatty acid metabolism playing a role in neurodevelopmental disorders such as autism. In order to definitely determine whether fatty acid concentrations were associated with autism, we quantitatively measured 30 fatty acids from seven
A A Bueno et al.
Journal of obstetrics and gynaecology : the journal of the Institute of Obstetrics and Gynaecology, 32(3), 241-246 (2012-03-01)
In Sudanese women with (n = 60) and without (n = 65) pre-eclampsia, circulating lipids, plasma and red cell saturated and monounsaturated fatty (MUFA) acids and dimethyl acetals (DMAs) were investigated. DMAs are an indirect marker of levels of plasmalogens

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