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Key Documents

178721

Sigma-Aldrich

(Diacetoxyiodo)benzene

98%

Sinonimo/i:

Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate

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About This Item

Formula condensata:
C6H5I(O2CCH3)2
Numero CAS:
Peso molecolare:
322.10
Beilstein:
1879369
Numero CE:
Numero MDL:
Codice UNSPSC:
12352002
ID PubChem:
NACRES:
NA.22

Livello qualitativo

Saggio

98%

Forma fisica

powder

Impiego in reazioni chimiche

reagent type: catalyst
reagent type: oxidant
reaction type: C-H Activation

Punto di fusione

161-163 °C (lit.)

Stringa SMILE

CC(OI(OC(C)=O)C1=CC=CC=C1)=O

InChI

1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
ZBIKORITPGTTGI-UHFFFAOYSA-N

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Applicazioni

Stoichiometric oxidant in the TEMPO oxidation of nerol to neral. Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
Used in the room temperature Pd-catalyzed 2-arylation of indoles
Useful reagent for the synthesis of a wide variety of heterocyclic compounds.

Prodotti correlati

N° Catalogo
Descrizione
Determinazione del prezzo

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)


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Articoli

New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.

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