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31277

Sigma-Aldrich

Cobalt(II) chloride hexahydrate

puriss. p.a., ACS reagent, reag. Ph. Eur., 98-102%

Sinônimo(s):

Cobaltous chloride hexahydrate

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About This Item

Fórmula linear:
CoCl2 · 6H2O
Número CAS:
7791-13-1
Peso molecular:
237.93
Número CE:
231-589-4
Número MDL:
MFCD00149652
Código UNSPSC:
12352302
ID de substância PubChem:
329753717
NACRES:
NB.24

grau

ACS reagent
puriss. p.a.

Nível de qualidade

200

Agency

reag. Ph. Eur.

pressão de vapor

40 mmHg ( 0 °C)

Ensaio

98-102%

Formulário

solid

Impurezas

≤0.01% water-insoluble matter

traços de ânion

nitrate (NO3-): ≤100 mg/kg
sulfate (SO42-): ≤50 mg/kg

traços de cátion

Ca: ≤50 mg/kg
Cu: ≤20 mg/kg
Fe: ≤50 mg/kg
K: ≤50 mg/kg
Mg: ≤10 mg/kg
Mn: ≤50 mg/kg
Na: ≤100 mg/kg
Ni: ≤500 mg/kg
Pb: ≤5 mg/kg
Zn: ≤25 mg/kg

cadeia de caracteres SMILES

O.O.O.O.O.O.Cl[Co]Cl

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

chave InChI

GFHNAMRJFCEERV-UHFFFAOYSA-L

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Descrição geral

Cobalt(II) chloride hexahydrate is a hydrated form of cobalt chloride. It is used as a catalyst for various organic reactions such as acetylation and tosylation of alcohols, chemoselective reduction of carboxylic esters, and condensation reactions.

Aplicação

Cobalt(II) chloride hexahydrate can be used as a catalyst:      
  • To convert various aldoximes into corresponding nitriles in the presence of an inorganic base.      
  • To prepare organic-inorganic polyvinylidene fluoride nanofiber composites (PVDF/CoCl2) for the production of pure hydrogen production from NaBH4.

It can also be used as a cobalt precursor to synthesize nickel-cobalt-based binary metal phosphide (NiCoP) hollow spheres, which are used for electrocatalysis and energy storage (supercapacitor) applications.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Certificados de análise (COA)

Lot/Batch Number
MKCQ2027
MKCP1366
MKCL9789
MKCK6702
MKCK2476

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