208256

Tin(II) chloride

reagent grade, 98%

• Sinônimo(s): Stannous chloride
• Fórmula linear: SnCl₂
• Número CAS: 7772-99-8
• Peso molecular: 189.62
• Número CE: 231-868-0
• Número MDL: MFCD00011241
• Código UNSPSC: 12352302
• ID de substância PubChem: 329752041
• NACRES: NA.21

Propriedades

• grau: reagent grade
• Nível de qualidade: 200
• pressão de vapor: 33 hPa (~429 °C)
• Ensaio: 98%
• Formulário: crystalline; powder or flakes
• pH: 2.18 (20 °C)
• p.e.: 652 °C (lit.)
• pf: 246 °C (lit.)
• cadeia de caracteres SMILES: Cl[SnH2]Cl
• InChI: 1S/2ClH.Sn/h2*1H;/q;;+2/p-2
• chave InChI: AXZWODMDQAVCJE-UHFFFAOYSA-L

Descrição

Descrição geral

SnCl₂ dihydrate reacts with acetic anhydride to yield anhydrous SnCl₂. SnCl₂ exhibits reducing properties in acidic media. SnCl₂ shows superior catalytic action in its molten state. It is a promising raw material for the chemical vapour deposition (CVD) of semiconducting layers. SnCl₂ participates in the reduction of aromatic nitro compounds, nitriles, cyanosilyl ethers and organic azides.

Aplicação

Tin(II) chloride (SnCl₂) has been used as a starting material to evaluate the thermal behavior of SnCl₂ on heating at the rate of 5°Cmin^-1 in air. The product undergoes phase transformation on heating at rate of 5°C min^-1 in air, it involves an incomplete evaporation followed by oxidation forming SnO₂ nanoparticles. SnCl₂ has also been used for the fabrication of Sn-containing carbon nano-structures.

Tin(II) chloride may be used:

• To catalyze the addition of diazo sulfones, diazo phosphine oxides and diazo phosphonates to aldehydes to form β-keto sulfones, β-keto phosphine oxides and β-keto phosphonates, respectively.
• Along with trityl chloride, to catalyze the aldol reaction of silyl enol ethers with acetals or aldehydes and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones.
• As a promoter in the allylic amination of allylic alcohols with amines in the presence of palladium catalyst.

Informações de segurança

• Pictogramas: GHS08,GHS05,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H290,H302 + H332,H314,H317,H335,H373,H412
• Declarações de precaução: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
• Órgãos-alvo: Cardio-vascular system, Respiratory system
• Código de classe de armazenamento: 8B - Non-combustible corrosive hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable