About This Item
Fórmula linear:
AlCl3
Número CAS:
Peso molecular:
133.34
Número CE:
Número MDL:
Código UNSPSC:
12352302
eCl@ss:
38120507
ID de substância PubChem:
NACRES:
NA.21
Produtos recomendados
grau
reagent grade
Nível de qualidade
pressão de vapor
1 mmHg ( 100 °C)
Ensaio
98%
Formulário
powder or chunks
adequação da reação
reagent type: catalyst
core: aluminum
pH
2.4 (20 °C, 100 g/L)
pf
190 °C (lit.)
cadeia de caracteres SMILES
Cl[Al](Cl)Cl
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
chave InChI
VSCWAEJMTAWNJL-UHFFFAOYSA-K
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Descrição geral
Aluminum chloride participates in the amination of exo-2-chloronorbornane to afford 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane. It has been reported to promote the Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene.
Aplicação
Aluminum chloride has been employed for the estimation of total contents of flavonoids in a freeze-dried extract isolated from Issopus officinalis. It has been employed for the synthesis of the following compounds:
- 3′-methyl-5′,6′,7′,7a′-tetrahydro-4′H-spiro(cyclohexane-1,1′-isobenzofuran)
- trans-methyl 2-(cyclohex-1-enyl)cyclohexyl ketone
- 1,1,3-trimethyl-1,4,5,6,7,7a-hexahydroisobenzofuran
- 1-((2R*,4aS*,8aR*)-2-methyldecahydronaphthalen-4ayl)ethanone
Aluminum chloride may be used as catalyst for the Friedel-Crafts polymerizations of 4-(trifluoromethoxy)benzyl bromide. It may be employed as catalyst for Fries rearrangement of phenyl isobutyrate at 140°C to afford a mixture of 2-hydroxy- and 4-hydroxy-isobutyrophenone.
It may be used to catalyze:
It may be used to catalyze:
- Degradation of polystyrene to benzene.
- Carbonization of polycyclic aromatic hydrocarbons.
- Colorimetric microassay of hydroperoxides.
Características e benefícios
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Dam. 1 - Skin Corr. 1B
Perigos de suplementos
Código de classe de armazenamento
8A - Combustible corrosive hazardous materials
Classe de risco de água (WGK)
WGK 1
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
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Carbonization of pitches-IV: Carbonization of polycyclic aromatic hydrocarbons under the presence of aluminum chloride catalyst.
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Carbon, 13(2), 135-139 (1975)
Aliphatic C-H activation with aluminium trichloride-acetyl chloride: expanding the scope of the Baddeley reaction for the functionalisation of saturated hydrocarbons.
Lyall CL, et al.
Organic & Biomolecular Chemistry, 11(9), 1468-1475 (2013)
Catalytic degradation of polystyrene in the presence of aluminum chloride catalyst.
Nanbu H, et al.
Polymer Degradation and Stability, 19(1), 61-76 (1987)
The obtaining of an antioxidant product based on Issopus officinalis freeze: Dried extract.
Emanuel V, et al.
Journal of Medicinal Plants Research, 5(10), 2078-2085 (2011)
A colorimetric microdetermination of peroxide values utilizing aluminum chloride as the catalyst.
Asakawa T and Matsushita S.
Lipids, 15(11), 965-967 (1980)
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