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205222

Sigma-Aldrich

Sodium cyanide

ACS reagent, ≥95.0%

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About This Item

Fórmula linear:
NaCN
Número CAS:
Peso molecular:
49.01
Beilstein:
3587243
Número CE:
Número MDL:
Código UNSPSC:
12352300
ID de substância PubChem:
NACRES:
NB.24

grau

ACS reagent

Nível de qualidade

densidade de vapor

1.7 (vs air)

pressão de vapor

1 mmHg ( 817 °C)

Ensaio

≥95.0%

forma

crystalline powder
powder, crystals or chunks

pH

11-12 (25 °C, 49 g/L)

pf

563.7 °C (lit.)

solubilidade

water: soluble(lit.)

traços de ânion

S2-: ≤0.005%
SCN-: ≤0.02%
chloride (Cl-): ≤0.15%
phosphate (PO43-): ≤0.02%
sulfate (SO42-): ≤0.05%

traços de cátion

Fe: ≤0.005%
Pb: ≤0.005%

cadeia de caracteres SMILES

[Na]C#N

InChI

1S/CN.Na/c1-2;

chave InChI

RTVFYQXEHKQMKO-UHFFFAOYSA-N

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Descrição geral

Sodium cyanide is colorless sodium salt and its crystals belong to the cubic crystal system. Its aqueous solutions are strongly basic due to the presence of cyanide ion. It can be synthesized by reacting sodium hydroxide with hydrogen cyanide. Sodium cyanide is a key precursor for the synthesis of various organic intermediates. It participates in the RuCl3-mediated oxidative cyanation of tertiary amines.

Aplicação

Sodium cyanide may be employed for the synthesis of the following compounds:
  • α-amino acids
  • Prussian blue (cyanide pigment)
  • nitriles, via reaction with primary and secondary chlorides

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 1 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 1

Órgãos-alvo

Thyroid

Perigos de suplementos

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3


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Daniela Gontero et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 19(9), 1168-1188 (2020-07-18)
Escherichia coli bacteria were determined by in flow cytometry with laser excitation and fluorescence detection applying ultraluminescent core-shell nanoparticles based on Metal Enhanced Fluorescence (MEF). Core-shell nanoparticles consisted of a 40 nm core modified with a silica spacer grafted with
Eagleson M.
Concise Encyclopedia Chemistry, 1037-1037 (1994)
Shun-Ichi Murahashi et al.
Journal of the American Chemical Society, 125(50), 15312-15313 (2003-12-11)
RuCl3-catalyzed oxidative cyanation of tertiary amines with sodium cyanide under molecular oxygen (1 atm) at 60 degrees C gives the corresponding alpha-aminonitriles, which are versatile synthetic intermediates of various compounds such as amino acids and unsymmetrical 1,2-diamines, in excellent yields.
Preparation of Nitriles from Halides and Sodium Cyanide. An Advantageous Nucleophilic Displacement in Dimethyl Sulfoxide1a.
Friedman L and Shechter H.
The Journal of Organic Chemistry, 25(6), 877-879 (1960)
Jian Tan et al.
Molecular vision, 17, 3300-3308 (2011-12-24)
Loss of retinal ganglion cells (RGCs) during retinal ischemia is the potentially blinding mechanism that underlies several sight-threatening disorders. Fluctuations in extracellular pH are associated with such pathological conditions. It has been demonstrated that the retina is a functionally distinct

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