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Documentos Principais

56816

Supelco

Clothianidin-d3

PESTANAL®, analytical standard

Sinônimo(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-(methyl-d3)-2-nitroguanidine

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About This Item

Fórmula empírica (Notação de Hill):
C6D3H5ClN5O2S
Número CAS:
Peso molecular:
252.70
Número MDL:
Código UNSPSC:
41116107
ID de substância PubChem:
NACRES:
NA.24

grau

analytical standard

Nível de qualidade

linha de produto

PESTANAL®

Ensaio

≥97.0% (HPLC)

prazo de validade

limited shelf life, expiry date on the label

técnica(s)

HPLC: suitable
gas chromatography (GC): suitable

aplicação(ões)

agriculture
environmental

Formato

neat

alteração de massa

M+3

cadeia de caracteres SMILES

[2H]C([2H])([2H])N\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/i1D3

chave InChI

PGOOBECODWQEAB-FIBGUPNXSA-N

Categorias relacionadas

Descrição geral

Find more information here: Neonicotinoids

Aplicação

Clothianidin-d3 may be used as a standard for the determination of neonicotinoid in milk by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Embalagem

Bottomless glass bottle. Contents are inside inserted fused cone.

Informações legais

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Exclamation markEnvironment

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Certificados de análise (COA)

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Development and Validation of an Ultra-Sensitive UHPLC-MS/MS Method for Neonicotinoid Analysis in Milk.
Lachat L and Glauser G
Journal of Agricultural and Food Chemistry, 66(32), 8639-8646 (2018)
Daniel B Pickford et al.
Environmental toxicology and chemistry, 37(4), 1040-1050 (2017-11-07)
Thiamethoxam is a widely used neonicotinoid insecticide that has been detected in surface water monitoring programs in North America and Europe. This has led to questions about its toxicity to nontarget insects, specifically those with an aquatic life stage. To
Lucas M Morrison et al.
Journal of AOAC International, 101(6), 1940-1947 (2018-05-23)
Background: Neonicotinoids are among the most widely used insecticides. Recently, there has been concern associated with unintended adverse effects on honeybees and aquatic invertebrates at low parts-per-trillion levels. Objective: There is a need for LC-MS/MS methods that are capable of
Samuel E Baker et al.
Analytical and bioanalytical chemistry, 411(3), 669-678 (2018-11-30)
Neonicotinoid insecticides are widely used replacements for organophosphate and carbamate insecticides, but the extent of human exposure is largely unknown. On the other hand, based on urinary concentrations of DEET metabolites, human exposure to N,N-diethyl-m-toluamide (DEET) appears to be widespread.
Arthur Schaafsma et al.
Environmental toxicology and chemistry, 35(2), 295-302 (2015-09-04)
Neonicotinoid insecticides, especially as seed treatments, have raised concerns about environmental loading and impacts on pollinators, biodiversity, and ecosystems. The authors measured concentrations of neonicotinoid residues in the top 5 cm of soil before planting of maize (corn) in 18 commercial

Protocolos

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.

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