471712

terc-Butanol

anhydrous, ≥99.5%

• Sinônimo(s): 2-metil-2-propanol, Álcool terc-butílico, Trimetilcarbinol
• Fórmula linear: (CH₃)₃COH
• Número CAS: 75-65-0
• Peso molecular: 74.12
• Beilstein: 906698
• Número CE: 200-889-7
• Número MDL: MFCD00004464
• Código UNSPSC: 12352001
• ID de substância PubChem: 57650901
• NACRES: NA.21

Propriedades

• grau: anhydrous
• Nível de qualidade: 100
• densidade de vapor: 2.5 (vs air)
• pressão de vapor: 31 mmHg ( 20 °C); 44 mmHg ( 26 °C)
• Ensaio: ≥99.5%
• forma: solid or liquid
• temperatura de autoignição: 896 °F
• Lim. expl.: 8 %
• Impurezas: <0.005% water
• resíduo de evaporação: <0.0003%
• índice de refração: n20/D 1.387 (lit.)
• pH: 7 (20 °C)
• pb: 83 °C (lit.)
• pf: 23-26 °C (lit.)
• solubilidade: water: miscible
• densidade: 0.775 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: CC(C)(C)O
• InChI: 1S/C4H10O/c1-4(2,3)5/h5H,1-3H3
• chave InChI: DKGAVHZHDRPRBM-UHFFFAOYSA-N

Descrição

Descrição geral

tert-Butanol (tBA) is a tertiary alcohol. It undergoes dehydration by reactive distillation in the presence of solid acid catalyst to form isobutylene with high selectivity. Lipase-mediated alcoholysis of soybean oil deodorizer distillate (SODD) has been conducted in tBA (as reaction medium) to generate biodiesel. Formation of 2-tert-butyl-p-cresol (TBC), 2,6-di-tert-butyl-p-cresol (DTBC) and tert-butyl-p-tolyl ether has been reported when p-cresol undergoes butylation by tBA in the presence of 12-tungstophosphoric acid supported on zirconia (TPA/ZrO₂) catalyst. The interaction behavior of tBA on the Si (001)-(2×1) surface has been assessed by using the ab-initio density functional theory (DFT) based on pseudopotential approach.

Aplicação

• Synthesis of Ribose - Oleic Acid Esters in the Presence- and Absence of Candida antarctica Lipase B.: This study investigates the synthesis of ribose-oleic acid esters using tert-Butanol as a solvent, both with and without the presence of Candida antarctica Lipase B. The research explores the efficiency and effectiveness of the enzyme-catalyzed process, highlighting the impact of tert-Butanol on the synthesis reaction. The findings contribute to the understanding of esterification processes in analytical chemistry and have potential applications in developing new synthetic methods (Çetinkaya et al., 2020).

Informações de segurança

• Pictogramas: GHS02,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H225,H319,H332,H335,H336
• Declarações de precaução: P210 - P233 - P240 - P241 - P304 + P340 + P312 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Órgãos-alvo: Central nervous system, Respiratory system
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): 59.0 °F - closed cup
• Ponto de fulgor (°C): 15 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter