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Documentos Principais

08953

Supelco

1-Bromobutane

analytical standard

Sinônimo(s):

Butyl bromide

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About This Item

Fórmula linear:
CH3(CH2)3Br
Número CAS:
Peso molecular:
137.02
Beilstein:
1098260
Número CE:
Número MDL:
Código UNSPSC:
41116107
ID de substância PubChem:
NACRES:
NA.24

grau

analytical standard

Nível de qualidade

densidade de vapor

4.7 (vs air)

pressão de vapor

150 mmHg ( 50 °C)
40 mmHg ( 25 °C)

Ensaio

≥99.5% (GC)

temperatura de autoignição

509 °F

prazo de validade

limited shelf life, expiry date on the label

Lim. expl.

2.8-6.6 %, 100 °F

técnica(s)

HPLC: suitable
gas chromatography (GC): suitable

índice de refração

n20/D 1.439 (lit.)
n20/D 1.440

p.e.

100-104 °C (lit.)

pf

−112 °C (lit.)

densidade

1.276 g/mL at 25 °C (lit.)

aplicação(ões)

environmental

Formato

neat

cadeia de caracteres SMILES

CCCCBr

InChI

1S/C4H9Br/c1-2-3-4-5/h2-4H2,1H3

chave InChI

MPPPKRYCTPRNTB-UHFFFAOYSA-N

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Descrição geral

1-Bromobutane, an organobromine compound, is a commonly used industrial solvent for cleaning, extraction and chemical synthesis.

Aplicação

1-Bromobutane may be used as a derivatization reagent for multiple functional groups (amino, carboxyl, and phenolic hydroxyl groups) of amino acids to improve hydrophobicities and basicities of the amino acids. It may also be used as an internal standard for the quantification of 1- and 2-bromopropane in human urine by headspace gas chromatography.

Palavra indicadora

Danger

Classificações de perigo

Aquatic Chronic 2 - Carc. 2 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

Órgãos-alvo

Liver, Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

50.0 °F - closed cup

Ponto de fulgor (°C)

10 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Thomas J Wood et al.
Chemical communications (Cambridge, England), 48(82), 10201-10203 (2012-09-11)
Highly ion-conducting poly(ionic liquid) thin films have been prepared in the absence of solvents utilizing a simple 2-step approach comprising pulsed plasmachemical deposition of 1-allylimidazole followed by vapour-phase quaternization with 1-bromobutane.
Martin Hesseler et al.
Applied microbiology and biotechnology, 91(4), 1049-1060 (2011-05-24)
A haloalkane dehalogenase (DppA) from Plesiocystis pacifica SIR-1 was identified by sequence comparison in the NCBI database, cloned, functionally expressed in Escherichia coli, purified, and biochemically characterized. The three-dimensional (3D) structure was determined by X-ray crystallography and has been refined
Josélia Larger Manfio et al.
Journal of AOAC International, 92(5), 1366-1372 (2009-11-18)
A sensitive and specific LC/MS/MS method was developed and validated for the determination of scopolamine butylbromide in human plasma. Scopolamine butylbromide and propanolol (internal standard) were extracted from the plasma by liquid-liquid extraction with dichloromethane as the extraction solvent and
Christina Lederle et al.
The Journal of chemical physics, 134(6), 064512-064512 (2011-02-17)
Mixtures of the monohydroxy alcohol n-butanol with n-bromobutane are investigated via dielectric and nuclear magnetic resonance (NMR) techniques. Static- and pulsed-field gradient proton NMR yielded self-diffusion coefficients as a function of concentration and temperature. To monitor reorientational motions, broadband dielectric
[Colic and spastic states of the urinary tract. Comparison between syntropium bromide (VAL 480) with ioscine n-butylbromide and with noramidopyrine-pitofenone-fenpiverinium bromide].
G M Colpi et al.
Minerva urologica e nefrologica = The Italian journal of urology and nephrology, 37(3), 341-348 (1985-07-01)

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