T87807
1,1,1-Tris(hydroxymethyl)ethane
≥98%
Sinônimo(s):
2-Hydroxymethyl-2-methyl-1,3-propanediol, Trimethylolethane
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About This Item
Fórmula linear:
CH3C(CH2OH)3
Número CAS:
Peso molecular:
120.15
Beilstein:
1304452
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
≥98%
pf
193-195 °C (lit.)
cadeia de caracteres SMILES
CC(CO)(CO)CO
InChI
1S/C5H12O3/c1-5(2-6,3-7)4-8/h6-8H,2-4H2,1H3
chave InChI
QXJQHYBHAIHNGG-UHFFFAOYSA-N
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Aplicação
1,1,1-Tris(hydroxymethyl)ethane can be used as a reactant to synthesize:
It can also be used as a tridentate O-donor ligand in the:
- Hyperbranched polyesters by polycondensation reaction with dimethyl esters of aliphatic dicarboxylic acids.
- Trimeric anionic surfactants by reacting with long-chain α-bromo fatty acids.
It can also be used as a tridentate O-donor ligand in the:
- Copper-catalyzed cross-coupling reactions between aryl iodides and amides, thiols, and phenols to prepare corresponding products via formation of C−N, C−S, and C−O bonds.
- N-arylation of azaheterocycles with aryl iodides using copper-catalyst.
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
320.0 °F - closed cup
Ponto de fulgor (°C)
160.00 °C - closed cup
Equipamento de proteção individual
Eyeshields, Gloves, type N95 (US)
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J. Chin. Chem. Soc., 57(1), 14-18 (2010)
Synthesis and surface-active properties of a homologous series of star-like triple-chain anionic surfactants derived from 1, 1, 1-tris (hydroxymethyl) ethane
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