T511609

(S)-TCYP

Aldrich^CPR

• Fórmula empírica (Notação de Hill): C₆₈H₈₁O₄P
• Peso molecular: 993.34
• Código UNSPSC: 12161600

Propriedades

• Nível de qualidade: 100
• adequação da reação: reagent type: ligand
• índice de refração: n/D
• grupo funcional: phosphine
• cadeia de caracteres SMILES: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)C6CCCCC6)C7CCCCC7
• InChI: 1S/C32H33O4P/c33-37(34)35-31-27(21-11-3-1-4-12-21)19-23-15-7-9-17-25(23)29(31)30-26-18-10-8-16-24(26)20-28(32(30)36-37)22-13-5-2-6-14-22/h7-10,15-22H,1-6,11-14H2,(H,33,34)
• chave InChI: RMVWMWZCAKQBAI-UHFFFAOYSA-N

Descrição

Descrição geral

(S)-TCYP is a chiral phosphoric acid catalyst that is commonly used in chemical synthesis. It has been found to be particularly effective in promoting enantioselective reactions. The sterically demanding triscyclohexylbenzene at the 3 and 3′ positions of (S)-TCYP contribute significant steric influence and ressult in its to its high levels of enantioselectivity.

Aplicação

(S)-TCYP has been used in asymmetric aza-ene-type reactions, catalyzing the formation of C-C bonds with high levels of diastereoselectivity

Outras notas

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Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable