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Documentos Principais

P14831

Sigma-Aldrich

Phenothiazine

≥98%

Sinônimo(s):

Dibenzo-1,4-thiazine, Thiodiphenylamine, 10H-Phenothiazine

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About This Item

Fórmula empírica (Notação de Hill):
C12H9NS
Número CAS:
Peso molecular:
199.27
Beilstein:
143237
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Ensaio

≥98%

p.e.

371 °C (lit.)

pf

182-187 °C (lit.)

cadeia de caracteres SMILES

N1c2ccccc2Sc3ccccc13

InChI

1S/C12H9NS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8,13H

chave InChI

WJFKNYWRSNBZNX-UHFFFAOYSA-N

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Descrição geral

Phenothiazine is a versatile building block that can be easily functionalized as it possesses multiple modification sites. Its unique butterfly configuration and electron-rich character are beneficial for its potential use in optoelectronic applications. As it can undergo fast and reversible electron transfer reactions, it is widely used as photoactive material in organic light-emitting devices and solar cells.

Aplicação

Phenothiazine can be used in the following applications:
  • It can be connected to carbazole by C-N linkage to increase the hole mobility and thermal stability in organic light-emitting devices.
  • Used in the fabrication of CMA-based (Carbene-Metal-Amide) white light-emitting OLED.
  • It is used as a starting material in the synthesis of dialdehyde monomer. A conjugated copolymer is prepared using this dialdehyde monomer, which is applicable as an emitting layer in PLED.
  • Used as a building block in the synthesis of conjugated dendrimers, for the development of light-emitting devices.

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1 - STOT RE 2 Oral

Órgãos-alvo

Blood

Código de classe de armazenamento

13 - Non Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Indian J. Chem. B, 33, 397-397 (1994)
Alexander S Romanov et al.
Chemical science, 11(2), 435-446 (2020-03-20)
Conformationally flexible "Carbene-Metal-Amide" (CMA) complexes of copper and gold have been developed based on a combination of sterically hindered cyclic (alkyl)(amino)carbene (CAAC) and 6- and 7-ring heterocyclic amide ligands. These complexes show photoemissions across the visible spectrum with PL quantum
Synthesis of p-type conjugated dendrimers bearing phenothiazine moiety at the periphery and their light-emitting device characterization
Dong Hoon Choi, et al.
Synthetic Metals, 157(8), 332-335 (2007)
Structure-induced optoelectronic properties of phenothiazine-based materials
Revoju, et al.
Journal of Material Chemistry C, 8(44), 15486-15506 (2020)
Rajendra Kumar Konidena et al.
The Journal of organic chemistry, 80(11), 5812-5823 (2015-05-08)
A series of thienylphenothiazine decorated carbazoles were synthesized and characterized by optical, electrochemical, thermal, and theoretical investigations. Absorption spectra of the compounds are influenced by the substitution pattern and chromophore number density. Compounds containing 2,7-substitution exhibited red-shifted absorption, while the

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