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Documentos Principais

A8524

Sigma-Aldrich

Aniline hydrochloride

≥99%

Sinônimo(s):

Anilinium chloride, Benzenamine hydrochloride, Phenylamine hydrochloride, Phenylammonium chloride

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About This Item

Fórmula linear:
C6H5NH2 · HCl
Número CAS:
Peso molecular:
129.59
Beilstein:
3593823
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

densidade de vapor

4.46 (vs air)

Ensaio

≥99%

Formulário

crystals

pf

196-198 °C (lit.)

cadeia de caracteres SMILES

Cl.Nc1ccccc1

InChI

1S/C6H7N.ClH/c7-6-4-2-1-3-5-6;/h1-5H,7H2;1H

chave InChI

MMCPOSDMTGQNKG-UHFFFAOYSA-N

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Ações bioquímicas/fisiológicas

The acute toxicity of aniline involves its activation in vivo to 4-hydroxyaniline and the formation of adducts with hemoglobin. In erythrocytes, this is associated with the release of iron and the accumulation of methemoglobin and the development of hemolytic anemia and inflammation of the spleen. Tumor formation is often observed in the spleen on prolonged administration.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

381.2 °F - closed cup

Ponto de fulgor (°C)

194 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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The synthesis and electrochemical oxidative coupling of a highly electron-deficient analogue of aniline results in the formation of soluble electron-deficient oligomers. Oligomers undergo related oxidation and reduction processes that are separated by a wide potential range. The mechanism behind this
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Femtosecond time-resolved photoelectron imaging is employed to investigate ultrafast electronic relaxation in aniline, a prototypical aromatic amine. The molecule is excited at wavelengths between 269 and 238 nm. We observe that the S2(pi3s/pi sigma*) state is populated directly during the

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