930008

RuCl(p-cymene)[(R,R)-Ts-DPEN]

• Sinônimo(s): [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
• Fórmula empírica (Notação de Hill): C₃₁H₃₅ClN₂O₂RuS
• Número CAS: 192139-92-7
• Peso molecular: 636.21
• Número MDL: MFCD10567385
• Código UNSPSC: 12352116
• NACRES: NA.21

Propriedades

• Formulário: powder or crystals
• Nível de qualidade: 100
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pf: 215 °C
• categoria alternativa mais ecológica: Aligned
• temperatura de armazenamento: 2-8°C
• cadeia de caracteres SMILES: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
• chave InChI: AZFNGPAYDKGCRB-AGEKDOICSA-M

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

• Quinolines
• N-Alkyl ketimines
• Antitumor and antiproliferative derivatives of natural products isolated from bacteria
• Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium used for asymmetric hydrogenation reactions.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable