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Documentos Principais

82320

Sigma-Aldrich

(±)-Propylene oxide

puriss. p.a., ≥99.5% (GC)

Sinônimo(s):

(±)-Methyloxirane, 1,2-Epoxypropane

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About This Item

Fórmula empírica (Notação de Hill):
C3H6O
Número CAS:
Peso molecular:
58.08
Beilstein:
79763
Número CE:
Número MDL:
Código UNSPSC:
12162002
ID de substância PubChem:
NACRES:
NA.23

densidade de vapor

2 (vs air)

Nível de qualidade

pressão de vapor

29.43 psi ( 55 °C)
8.59 psi ( 20 °C)

grau

puriss. p.a.

Ensaio

≥99.5% (GC)

Formulário

liquid

temperatura de autoignição

1378 °F

Lim. expl.

37 %

Impurezas

≤0.1% water

resíduo de evaporação

≤0.005%

índice de refração

n20/D 1.366 (lit.)
n20/D 1.366

p.e.

34 °C (lit.)

pf

−112 °C (lit.)

densidade

0.83 g/mL at 25 °C (lit.)

traços de cátion

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Condições de expedição

wet ice

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CC1CO1

InChI

1S/C3H6O/c1-3-2-4-3/h3H,2H2,1H3

chave InChI

GOOHAUXETOMSMM-UHFFFAOYSA-N

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Descrição geral

(±)-Propylene oxide (PPO) belongs to the class of monomers known as epoxides or oxiranes. It is used as a raw material in the preparation n of polyurethane foam and polyether polyols, which are used in the production of polyurethane elastomers, polyurethane plastics, adhesives, sealants, and coatings. These materials find applications in industries such as automotive, construction, electronics, and textiles. PPO-based polymers possess flexibility and elasticity as inherent properties, making them well-suited for applications that demand materials with excellent resilience, stretchability, and impact resistance. Additionally, PPO-derived polymers are biocompatible, which makes them suitable for applications in various fields such as biomedical engineering, drug delivery, and tissue engineering.

Aplicação

Propylene oxide can be used as a starting material to synthesize:
  • Poly(3-hydroxybutyrate), a biodegradable and biocompatible polyester, by carbonylative polymerization.
  • Poly (propylene-ram-ε-caprolactone carbonate) (PPCL) and poly (propylene carbonate) (PPC), which are applicable as drug carriers.
Propylene oxide may be used in the production of polyether polyols, propylene glycols, propylene glycol ethers.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 1B - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

-36.4 °F - Equilibrium method

Ponto de fulgor (°C)

-38 °C - Equilibrium method

Equipamento de proteção individual

Faceshields, Gloves, Goggles


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The aqueous gelation of a quaternary ammonium oligo(propylene oxide)-based ionic liquid yields ion gels with a reverse thermoresponsive behavior (i.e., mechanical moduli and viscosity increase with temperature) and enhanced ionic conductivities.
Aude Bouchet et al.
The Journal of organic chemistry, 76(10), 4178-4181 (2011-04-08)
ECD and NMR experiments show that the complexation of propylene oxide (PrO) within the cavity of an enantiopure water-soluble cryptophane 1 in NaOH solution is enantioselective and that the (R)-PrO@PP-1 diastereomer is more stable than the (S)-PrO@PP-1 diastereomer with a
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Journal of magnetic resonance (San Diego, Calif. : 1997), 209(2), 315-322 (2011-02-25)
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Chirality recognition in the hydrogen-bonded glycidol···propylene oxide complex has been studied by using rotational spectroscopy and ab initio calculations. An extensive conformational search has been performed for this binary adduct at the MP2/6-311++G(d,p) level of theory and a total of
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