804320

Potassium 4-ethoxycarbonylbenzoyltrifluoroborate

• Fórmula empírica (Notação de Hill): C₁₀H₉BF₃KO₃
• Número CAS: 1622923-40-3
• Peso molecular: 284.08
• Código UNSPSC: 12352103
• ID de substância PubChem: 329768861
• NACRES: NA.22

Propriedades

• forma: powder
• Nível de qualidade: 100
• pf: 228.00 °C
• cadeia de caracteres SMILES: O=C(B(F)(F)F)C1=CC=C(C(OCC)=O)C=C1.[K]
• InChI: 1S/C10H9BF3O3.K.H/c1-2-17-10(16)8-5-3-7(4-6-8)9(15)11(12,13)14;;/h3-6H,2H2,1H3;;
• chave InChI: YXYMQBSRJGUKGK-UHFFFAOYSA-N

Descrição

Aplicação

Acyltrifluroborates (KATs) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group

Outras notas

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation; Properties; and Reactivities

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable