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Merck
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Key Documents

792071

Sigma-Aldrich

Spiro-MeOTAD

greener alternative

99% (HPLC)

Sinônimo(s):

N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine, Spiro-OMeTAD

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About This Item

Fórmula empírica (Notação de Hill):
C81H68N4O8
Número CAS:
Peso molecular:
1225.43
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Ensaio

99% (HPLC)

forma

solid

características do produto alternativo mais ecológico

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

pf

243-248 °C

λmax

306 nm in dichloromethane
385 nm in dichloromethane

fluorescência

λem 429 nm in dichloromethane

categoria alternativa mais ecológica

cadeia de caracteres SMILES

COC(C=C1)=CC=C1N(C2=CC=C(C=C2)OC)C(C=C3)=CC4=C3C(C=CC(N(C5=CC=C(C=C5)OC)C6=CC=C(C=C6)OC)=C7)=C7C84C9=C(C=CC(N(C%10=CC=C(C=C%10)OC)C%11=CC=C(C=C%11)OC)=C9)C%12=C8C=C(N(C%13=CC=C(C=C%13)OC)C%14=CC=C(C=C%14)OC)C=C%12

InChI

1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3

chave InChI

XDXWNHPWWKGTKO-UHFFFAOYSA-N

Descrição geral

We are committed to bringing you Greener Alternative Products,which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an enabling product used as a Hole Transport Material for high-performance solar cells and thus has been enhanced for energy efficiency. Click here for more information.

Aplicação

High-mobility material used for white OLEDs to increase hole injection and transport. It is the best solid-state hole transporting material, to date, used to replace the liquid electrolyte for DSSC solar cells, due to an excellent pore-filling property in nanoporous TiO2 film with pore size of around 30-50 nm; attributed to its small molecular size.

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable


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Slide 1 of 3

1 of 3

Lining He et al.
ACS applied materials & interfaces, 4(3), 1704-1708 (2012-03-07)
High-efficiency hybrid solar cells are fabricated using a simple approach of spin coating a transparent hole transporting organic small molecule, 2,2',7,7'-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene (Spiro-OMeTAD) on silicon nanowires (SiNWs) arrays prepared by electroless chemical etching. The characteristics of the hybrid cells are investigated
Chemical compatibility between a hole conductor and organic dye enhances the photovoltaic performance of solid-state dye-sensitized solar cells
Young Soo Kwon,
Journal of Materials Chemistry, 22(17), 8641-8648 (2012)
Jingqi Liu et al.
Scientific reports, 9(1), 1362-1362 (2019-02-06)
Previously, textile dye sensitised solar cells (DSSCs) woven using photovoltaic (PV) yarns have been demonstrated but there are challenges in their implementation arising from the mechanical forces in the weaving process, evaporation of the liquid electrolyte and partially shaded cells

Artigos

Solar panels for homes and businesses have seen a rise in demand over the past few years as we move toward more environment-friendly and sustainable energy sources. In 2010, the average power from solar was just 5.0 GWh/d and the Energy Information Administration (EIA) expects this to be 90 GWh/d in 2016.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Advances in the area of soft optoelectronics, with a focus on the development of organic optoelectronic devices on shape memory polymers (SMP) is discussed.

Next generation solar cells have the potential to achieve conversion efficiencies beyond the Shockley-Queisser (S-Q) limit while also significantly lowering production costs.

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Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.

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