714852
1,8-Diazabicyclo[5.4.0]undec-7-ene solution
1 M in THF
Sinônimo(s):
DBU solution
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About This Item
Produtos recomendados
Formulário
liquid
concentração
1 M in THF
índice de refração
n20/D 1.425
densidade
0.899 g/mL at 25 °C
cadeia de caracteres SMILES
C1CCN2CCCN=C2CC1
InChI
1S/C9H16N2/c1-2-5-9-10-6-4-8-11(9)7-3-1/h1-8H2
chave InChI
GQHTUMJGOHRCHB-UHFFFAOYSA-N
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Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
Órgãos-alvo
Respiratory system
Perigos de suplementos
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 2
Ponto de fulgor (°F)
-0.0 °F
Ponto de fulgor (°C)
-17.8 °C
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Organic letters, 13(2), 292-295 (2010-12-15)
A pH-controlled fluorescence switch based on a core-substituted naphthalenediimide compound (NDI-DBU) was constructed. The novel pentacyclic compound (NDI-DBU) was derived from naphthalenediimide (NDI) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in only one synthetic operation, catalysized by CuI.
Nature chemistry, 1(9), 729-732 (2010-12-03)
Circularly polarized light (CPL) emitted from star-forming regions is an attractive candidate as a cause of single chirality in nature. It has remained difficult, however, to translate the relatively small chemical effects observed on irradiation of molecular systems with CPL
Angewandte Chemie (International ed. in English), 48(19), 3482-3485 (2009-04-08)
Why beat about the bush? An operationally simple and mild reaction based on the direct fixation of (11)CO(2) with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) has been developed for the synthesis of (11)C-labeled carbamates at 75 degrees C within 10 minutes in radiochemical yields
Chemistry (Weinheim an der Bergstrasse, Germany), 13(13), 3701-3706 (2007-01-20)
Reactions of salicylaldehydes with ethyl buta-2,3-dienoate or penta-3,4-dien-2-one catalyzed by a catalytic amount of potassium carbonate produce the corresponding 2 H-chromene products in moderate to good yields under mild conditions. A plausible reaction mechanism is discussed in the light of
Highly efficient organosuperbase-catalyzed Mannich-type reactions of sulfonylimidates with imines: successful use of aliphatic imines as substrates and a unique reaction mechanism.
Angewandte Chemie (International ed. in English), 51(38), 9525-9529 (2012-08-30)
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