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672068

Sigma-Aldrich

Vinylphosphonic acid

≥90% (T)

Sinônimo(s):

Ethenephosphonic acid, Ethylenephosphonic acid, P-Ethenylphosphonic acid

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About This Item

Fórmula linear:
CH2=CHP(O)(OH)2
Número CAS:
1746-03-8
Peso molecular:
108.03
Beilstein:
1741622
Número CE:
217-123-2
Número MDL:
MFCD00043866
Código UNSPSC:
12352100
ID de substância PubChem:
329760454
NACRES:
NA.22

Nível de qualidade

100

Ensaio

≥90% (T)

Impurezas

≤7.0% water

pf

36 °C (Lit. dry VPA) (lit.)

densidade

1.37 g/mL at 20 °C (lit.)

cadeia de caracteres SMILES

OP(O)(=O)C=C

InChI

1S/C2H5O3P/c1-2-6(3,4)5/h2H,1H2,(H2,3,4,5)

chave InChI

ZTWTYVWXUKTLCP-UHFFFAOYSA-N

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Aplicação

Vinylphosphonic acid (VPA) can be used as a monomer unit for the synthesis of poly(vinylphosphonic acid) via free radical polymerization. It is also used to develop copolymers of VPA with acrylonitrile, N-isopropylacrylamide, styrene, vinylpyrrolidone, and acrylic and methacrylic acid. These copolymers find potential application in hydrogels, drug delivery, biomimetic mineralization, and polymer electrolyte membranes in fuel cells.
It can also be used as an organic building block to prepare (E)-styryl phosphonic acid derivatives by reacting with various aryl halides via Pd-catalyzed Heck coupling reaction.

Pictogramas

Corrosion
GHS05

Palavra indicadora

Danger

Frases de perigo

H290 - H314

Classificações de perigo

Met. Corr. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible, corrosive hazardous materials

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

467.6 °F

Ponto de fulgor (°C)

242 °C

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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Sadegh Rostamnia et al.
Journal of combinatorial chemistry, 11(1), 143-145 (2008-12-23)
Trisubstituted vinylphosphonates have been prepared via three-component reaction using phosphites, acetylenic esters, and aroyl chlorides in good yields. A variety of phosphites, activated acetylenes, and aroyl chlorides have been successfully employed in these reactions. In addition, three-component synthesis of vinylphosphonate
Zara A Doddridge et al.
Biochemistry, 42(11), 3239-3246 (2003-03-19)
We have previously reported the synthesis of vinylphosphonate-linked thymidine dimers and their incorporation into synthetic oligonucleotides to create vinylphosphonate internucleotide linkages in the DNA. Such linkages have a profound effect on DNA backbone rotational flexibility, and we have shown that
Stephan Salzinger et al.
Macromolecular rapid communications, 33(16), 1327-1345 (2012-07-11)
Recent studies have shown that poly(vinylphosphonate)s are readily accessible by rare earth metal-mediated group transfer polymerization (GTP). This article highlights the progress in this new field and advantages of GTP in comparison to classical anionic and radical polymerization approaches. Late
Xuequan Lu et al.
The Journal of organic chemistry, 74(8), 3192-3195 (2009-03-20)
The first enantioselective synthesis of chiral isosteric phosphonate analogues of FTY720 is described. One of these analogues, FTY720-(E)-vinylphosphonate (S)-5, but not its R enantiomer, elicited a potent antiapoptotic effect in intestinal epithelial cells, suggesting that it exerts its action via
Ozlem Dogan et al.
Langmuir : the ACS journal of surfaces and colloids, 22(23), 9671-9675 (2006-11-01)
In the present work, copolymers of vinylphosphonic acid and 4-vinilyimidazole (poly(4-VIm-co-VPA)) were found to be substrates favoring the precipitation of nanohydroxyapatite (HAP) crystals from stable supersaturated solutions at pH 7.4 and 37 degrees C. Deposition kinetics were studied by the
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