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563110

Sigma-Aldrich

Diethyl azodicarboxylate solution

40 wt. % in toluene

Sinônimo(s):

1,2-Ethoxycarbonyl diazene solution, DEAD, Diethoxycarbonyldiazene solution, Diethyl azodiformate solution, NSC 3474, NSC 679015, Unifoam AZ-AE 200

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About This Item

Fórmula linear:
C2H5OCON=NCOOC2H5
Número CAS:
1972-28-7
Peso molecular:
174.15
Beilstein:
908662
Número MDL:
MFCD00009103
Código UNSPSC:
12352108
ID de substância PubChem:
24880080

Nível de qualidade

100

concentração

40 wt. % in toluene

índice de refração

n20/D 1.4690

pb

116-117 °C

densidade

0.956 g/mL at 25 °C

grupo funcional

azo

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CCOC(=O)\N=N/C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

chave InChI

FAMRKDQNMBBFBR-BQYQJAHWSA-N

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Descrição geral

DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.

Aplicação

Reactant for preparation of:
  • Immunostimulants α-Galactosylceramides
  • Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases
  • Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase
  • Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities
  • Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes

Reagent for:
  • Annulation of N-protected imines
  • α-thiocyanation of enolizable ketones with ammonium thiocyanate
  • Diels-Alder reactions
A commonly used activating reagent in Mitsunobo reactions.

Embalagem

100g unit contains ca. 40g DEAD solute
25g unit contains ca. 10g DEAD solute

Advertência

Toxic, Irritant, Flammable

Palavra indicadora

Danger

Classificações de perigo

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Self-react. C - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Órgãos-alvo

Central nervous system, Respiratory system

Código de classe de armazenamento

5.2 - Organic peroxides and self-reacting hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

105.8 °F - closed cup

Ponto de fulgor (°C)

41 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
MKCM8638
MKCL0488
MKCJ1314
MKCF3967
MKCC6724

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