477494
2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine
99%
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About This Item
Fórmula empírica (Notação de Hill):
C17H23N3O2
Número CAS:
Peso molecular:
301.38
Número MDL:
Código UNSPSC:
12352005
ID de substância PubChem:
NACRES:
NA.22
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Nível de qualidade
Ensaio
99%
atividade óptica
[α]20/D +118°, c = 0.7 in methylene chloride
pf
154-156 °C (lit.)
grupo funcional
ether
cadeia de caracteres SMILES
CC(C)[C@@H]1COC(=N1)c2cccc(n2)C3=N[C@@H](CO3)C(C)C
InChI
1S/C17H23N3O2/c1-10(2)14-8-21-16(19-14)12-6-5-7-13(18-12)17-20-15(9-22-17)11(3)4/h5-7,10-11,14-15H,8-9H2,1-4H3/t14-,15-/m0/s1
chave InChI
CSGQGLBCAHGJDR-GJZGRUSLSA-N
Categorias relacionadas
Aplicação
C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Iryna D Alshakova et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(50), 11734-11744 (2019-07-19)
This work unveils the reactivity patterns, as well as ligand and additive effect on alkali-metal-base-catalyzed transfer hydrogenation of ketones. Crucially to this reactivity is the presence of a Lewis acid (alkali cation), as opposed to a simple base effect. With
Pfaltz, A.
Accounts of Chemical Research, 26, 339-339 (1993)
Bolm, C.
Angewandte Chemie (International Edition in English), 30, 542-542 (1991)
Gant, T.G. Meyers, A.I.
Tetrahedron, 50, 2297-2297 (1994)
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