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463779

Sigma-Aldrich

Cloreto de rutênio (III)

99.98% trace metals basis

Sinônimo(s):

Trichlororuthenium hydrate, Ruthenium trichloride

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About This Item

Fórmula linear:
RuCl3 · xH2O
Número CAS:
14898-67-0
Peso molecular:
207.43 (anhydrous basis)
Número CE:
233-167-5
Número MDL:
MFCD00149844
Código UNSPSC:
12352302
ID de substância PubChem:
24870096
NACRES:
NA.23
Ensaio:
99.98% trace metals basis
Formulário:
powder and chunks

Nível de qualidade

100

Ensaio

99.98% trace metals basis

Formulário

powder and chunks

adequação da reação

reagent type: catalyst
core: ruthenium

Impurezas

≤250.0 ppm Trace Metal Analysis

cadeia de caracteres SMILES

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

chave InChI

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Descrição geral

Ruthenium(III) chloride hydrate exhibits excellent catalytic activity, attributed to the redox properties of ruthenium suitable for fuel cells and other electrochemical devices. It has ability to facilitate charge transfer and exhibit photoactive behavior.

Aplicação

Ruthenium(III) chloride hydrate can be used:
  • As a precursor to prepare ultralow Ru loaded graphene aerogel that exhibits electrocatalytic performance in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
  • As a dopant to prepare Ru-doped TiO2 electron transport layer for mesoscopic perovskite solar cell by spin-coating technique. This helps to enhance photoconversion efficiency and air stability.
  • To fabricate ultra-uniform Ru nanocluster catalyst via small-molecule self-assembly pyrolysis method. These catalysts exhibit excellent hydrogen evolution activity in Zinc air batteries under all pH conditions.

Outras notas

soluble form

Palavra indicadora

Danger

Frases de perigo

H302,H314,H411

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

8A - Combustible corrosive hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Escolha uma das versões mais recentes:

Certificados de análise (COA)

Lot/Batch Number
MKCP8815
MKCN5561
MKCN2590
MKCM9321
MKCM3277

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Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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