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Key Documents

434787

Sigma-Aldrich

Polybutadiene

average Mn ~3,000 by VPO

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About This Item

Fórmula linear:
(CH2CH=CHCH2)n
Número CAS:
Número MDL:
Código UNSPSC:
12162002
ID de substância PubChem:

descrição

peroxide number <= 10 mval/kg

forma

viscous liquid

peso molecular

average Mn ~3,000 by VPO

composição

cis-1,4, 75%
trans-1,4, 24%
vinyl, 1%

índice de refração

n20/D 1.524

viscosidade

2,700-3,000 mPa.s(20 °C)(lit.)

pf

−6 °C

número de acidez

≤0.3 mg KOH/g

valor de iodo

420‑480 g/100g

temperatura de transição

pour point ~−50 °C

solubilidade

aliphatic hydrocarbons: soluble

densidade

0.9 g/mL at 25 °C (lit.)

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

chave InChI

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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Aplicação

Co-reactant for air curing coatings.

Características e benefícios

Low viscosity liquid that undergoes polymerization in the presence of oxygen and free radical generators. Unsaponifiable drying oil. Improves water and chemical resistance.

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


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Gregory P Robbins et al.
Langmuir : the ACS journal of surfaces and colloids, 26(17), 14089-14096 (2010-08-14)
The polymersome, a fully synthetic cell mimetic, is a tunable platform for drug delivery vehicles to detect and treat disease (theranostics). Here, we design a leuko-polymersome, a polymersome with the adhesive properties of leukocytes, which can effectively bind to inflammatory
Joan M Widin et al.
Journal of the American Chemical Society, 134(8), 3834-3844 (2012-01-28)
Controlled/"living" polymerizations and tandem polymerization methodologies offer enticing opportunities to enchain a wide variety of monomers into new, functional block copolymer materials with unusual physical properties. However, the use of these synthetic methods often introduces nontrivial molecular weight polydispersities, a
P S Brown et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13712-13719 (2012-09-13)
Two-dimensional hexagonally ordered honeycomb surfaces have been created by solvent casting polybutadiene films under controlled humidity. Subsequent CF(4) plasmachemical fluorination introduces cross-linking and surface texturing, leading to hierarchical surfaces with roughness on both the 10 μm (honeycomb) and micrometer (texturing)
Zhi-ping Huang et al.
Journal of hazardous materials, 229-230, 251-257 (2012-06-26)
Migration appeared in the interfaces of nitrate ester plasticized polyether (NEPE) based propellant/hydroxyl-terminated polybutadiene (HTPB) based liner/ethylene propylene terpolymer (EPDM) based insulation was studied by aging at different temperatures. The migration components were extracted with solvent and determined by high
Rachel Calvet et al.
Journal of chromatography. A, 1253, 164-170 (2012-07-24)
In this study, the coupling of IGC-ID analysis and carbon blacks impregnation with increasing ratios of polymer allow us to highlight the affinity of the polymer to the solid surface. The variations of the dispersive component of the surface energy

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