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431567

Sigma-Aldrich

Lithium perchlorate

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99.99% trace metals basis

Sinônimo(s):

Perchloric acid, lithium salt

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About This Item

Fórmula linear:
LiClO4
Número CAS:
Peso molecular:
106.39
Número CE:
Número MDL:
Código UNSPSC:
12352302
ID de substância PubChem:
NACRES:
NA.23

grau

ACS reagent

Ensaio

99.99% trace metals basis

Formulário

granular

adequação da reação

reagent type: oxidant

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sustainability

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Impurezas

≤0.005% insolubles
<100 ppm total metallic impurities

pH

6.0-7.5

pf

236 °C (lit.)

solubilidade

H2O: 106.4 g/L at 20 °C

traços de ânion

chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤0.001%

categoria alternativa mais ecológica

cadeia de caracteres SMILES

[Li+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

chave InChI

MHCFAGZWMAWTNR-UHFFFAOYSA-M

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Descrição geral

Lithium perchlorate is a white salt that easily dissolves in water. It is commonly employed as an electrolytic salt in batteries due to its excellent electrical impedance, conductivity, hygroscopicity, and anodic stability properties. These characteristics are crucial for its role in battery applications. In addition, it is as a strong oxidizing agent and hence is used as an oxidizer in solid rocket propellants and organic reactions.
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Aplicação

Lithium perchlorate can be used:
  • As a precursor to prepare solid polymer electrolytes for rechargeable Li-ion batteries.
  • As an oxidizer to prepare polymer-based solid propellants.
  • To fabricate cobalt sulfide (CoS)-based counter electrode for dye-sensitized solar cells(DSSC).
Our Lithium perchlorate, with a 99.99% trace metals basis, possesses specific specifications that make it ideal for Lithium-ion batteries. It has low levels of anion traces such as chloride (Cl-): ≤0.003%and sulfate (SO42-): ≤0.001%. Additionally, it contains less than 5 ppm of heavy metals, further enhancing its suitability as an electrolytic salt for Lithium-ion batteries.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

5.1A - Strongly oxidizing hazardous materials

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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[reaction: see text] N-Acyliminium cation of prolines was efficiently generated to accumulate in an undivided cell at 0 degrees C by an anodic oxidation of N-acylprolines or alpha'-phenylsulfanylated N-acylproline derivatives in a lithium perchlorate/nitromethane solution. The iminium cation intermediates gave
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The interaction behaviours between components of polyacrylate (PAc)/poly(ethylene oxide) (PEO) and lithium perchlorate (LiClO(4)) were investigated in detail by Attenuated Total Reflectance (ATR)-Fourier Transformed Infrared (FTIR) spectroscopy. Solution cast films of the PAc/PEO and PAc/PEO/LiClO(4) were examined. No obvious shifting
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Proceedings of the National Academy of Sciences of the United States of America, 99(8), 5012-5017 (2002-04-18)
The adsorption of the trigonal connector, 1,3,5-tris[10-(3-ethylthiopropyl)dimethylsilyl-1,10-dicarba-closo-decaboran-1-yl]benzene (1), from acetonitrile/0.1 M LiClO(4) on the surface of mercury at potentials ranging from +0.3 to -1.4 V (vs. aqueous Ag/AgCl/1 M LiCl) was examined by voltammetry, Langmuir isotherms at controlled potentials, and
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A process of dibutyl sulphide (DBS) electro-oxidation using electrolysis and cyclic voltamperometry was investigated in water-methanol solution using different electrodes (platinum, boron doped diamond, graphite and glassy carbon). Obtained results indicate that the DBS electro-oxidation process is irreversible in voltamperometric
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Functionalized keto-enamines 6 were obtained by nucleophilic addition of enol ethers to the imine moiety of 2-azadienes derived from dehydroaspartic esters 4. Reactions of 2-azadiene 4c containing three electron-withdrawing substituents (CO(2)R) with enol ethers 5 in the presence of lithium

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