397229

Acetanilide

purified by sublimation, ≥99.9%

• Sinônimo(s): N-Phenylacetamide
• Fórmula linear: CH₃CONHC₆H₅
• Número CAS: 103-84-4
• Peso molecular: 135.16
• Beilstein: 606468
• Número CE: 203-150-7
• Número MDL: MFCD00008674
• Código UNSPSC: 12352100
• eCl@ss: 39031308
• ID de substância PubChem: 24864694
• NACRES: NA.22

Propriedades

• densidade de vapor: 4.65 (vs air)
• pressão de vapor: 1 mmHg ( 114 °C)
• Ensaio: ≥99.9%
• Formulário: solid
• temperatura de autoignição: 1004 °F
• purificado por: sublimation
• p.e.: 304 °C (lit.)
• pf: 113-115 °C (lit.)
• grupo funcional: amide
• cadeia de caracteres SMILES: CC(=O)Nc1ccccc1
• InChI: 1S/C8H9NO/c1-7(10)9-8-5-3-2-4-6-8/h2-6H,1H3,(H,9,10)
• chave InChI: FZERHIULMFGESH-UHFFFAOYSA-N

Descrição

Descrição geral

Pd(OAc)₂ and Cu(OAc)₂ catalyzed regioselective C-H functionalization/halogenation of acetanilide has been reported to afford ortho-haloacetanilides. Crystal structure of acetanilide has been studied by X-ray diffraction. Photorearrangement of acetanilide has been studied in the presence of β-cyclodextrin (cycloheptaamylose). Two-color REMPI (resonance enhanced multiphoton ionization) and ZEKE (zero kinetic energy photoelectron) spectra of the trans-acetanilide·H₂O complex has been reported. Femtosecond IR spectroscopy of delocalized NH excitations of crystalline acetanilide has been studied. Fries rearrangement of acetanilide over zeolites Y and Beta affords corresponding aminoacetophenones.

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H302
• Declarações de precaução: P264 - P270 - P301 + P312 - P501
• Classificações de perigo: Acute Tox. 4 Oral
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 1
• Ponto de fulgor (°F): 321.8 °F - closed cup
• Ponto de fulgor (°C): 161 °C - closed cup
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves