About This Item
Fórmula empírica (Notação de Hill):
C17H22O
Número CAS:
Peso molecular:
242.36
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Nível de qualidade
Ensaio
99%
Formulário
powder
pf
128-130 °C (lit.)
cadeia de caracteres SMILES
Cc1ccc(O)c(c1)C23C[C@H]4C[C@H](C[C@H](C4)C2)C3
InChI
1S/C17H22O/c1-11-2-3-16(18)15(4-11)17-8-12-5-13(9-17)7-14(6-12)10-17/h2-4,12-14,18H,5-10H2,1H3/t12-,13+,14-,17-
chave InChI
XHLJIHBDAJFXBE-ZZNDEYBLSA-N
Categorias relacionadas
Descrição geral
2-(1-Adamantyl)-4-methylphenol is a 2-adamantylphenol derivative. It has been synthesized by the adamantylation of p-cresol with 1-adamantanol. The structure has been confirmed by 1H and 13C NMR.
Aplicação
2-(1-Adamantyl)-4-methylphenol is a suitable starting reagent used in the synthesis of 2-(1-adamantyl)-4-methylthiophenol. It may also be used in the synthesis of 3-(1-adamantyl)-2-hydroxy-5-methylbenzaldehyde by reacting with urotropin. It may be used in the synthesis of adamantyl-substituted chromium(III) complex, a catalyst for enantioselective hetero-Diels-Alder reactions.
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
Escolha uma das versões mais recentes:
Já possui este produto?
Encontre a documentação dos produtos que você adquiriu recentemente na biblioteca de documentos.
Reactions of 2-hydroxymethylphenols with Lawesson's reagent.
Osyanin VA, et al
Chemistry of Heterocyclic Compounds, 47(7), 901-905 (2011)
Synthesis of 2, 4-disubstituted thiophenols and solid state structures of thiocarbamate precursors.
Flores-Figueroa A, et al
Journal of the Brazilian Chemical Society, 16.3A, 397-403 (2005)
Highly Enantio-and Diastereoselective Hetero-Diels?Alder Reactions Catalyzed by New Chiral Tridentate Chromium (iii) Catalysts.
Dossetter AG, et al.
Angewandte Chemie (International Edition in English), 38(16), 2398-2400 (1999)
Nan Wang et al.
Beilstein journal of organic chemistry, 8, 227-233 (2012-03-17)
A clean process has been developed for the synthesis of 2-adamantylphenol derivatives through adamantylation of substituted phenols with adamantanols catalyzed by commercially available and recyclable ion-exchange sulfonic acid resin in acetic acid. The sole byproduct of the adamantylation reaction, namely
Nossa equipe de cientistas tem experiência em todas as áreas de pesquisa, incluindo Life Sciences, ciência de materiais, síntese química, cromatografia, química analítica e muitas outras.
Entre em contato com a assistência técnica