391433

tert-Butylamine

≥99.5%

• Sinônimo(s): 2-Amino-2-methylpropane
• Fórmula linear: (CH₃)₃CNH₂
• Número CAS: 75-64-9
• Peso molecular: 73.14
• Beilstein: 605267
• Número CE: 200-888-1
• Número MDL: MFCD00008050
• Código UNSPSC: 12352100
• ID de substância PubChem: 24864378
• NACRES: NA.22

Propriedades

• densidade de vapor: 2.5 (vs air)
• Nível de qualidade: 300
• pressão de vapor: 5.7 psi ( 20 °C)
• Ensaio: ≥99.5%
• forma: liquid
• temperatura de autoignição: 716 °F
• Lim. expl.: 9.8 %
• índice de refração: n20/D 1.377 (lit.)
• pb: 46 °C (lit.)
• pf: −67 °C (lit.)
• solubilidade: water: miscible 1000 g/L at 25 °C; alcohol: miscible(lit.); chloroform: soluble(lit.); organic solvents: soluble(lit.)
• densidade: 0.696 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: CC(C)(C)N
• InChI: 1S/C4H11N/c1-4(2,3)5/h5H2,1-3H3
• chave InChI: YBRBMKDOPFTVDT-UHFFFAOYSA-N

Descrição

Descrição geral

tert-Butylamine (TBA) is an aliphatic primary amine. Its enthalpy of combustion and formation has been studied. Its gas phase acidity and gas phase basicity has been evaluated. The ozonation of tert-butylamine has been reported. Its influence on the aqueous beta-cyclodextrin (β-CD): pyrene complex has been examined by steady-state fluorescence measurements.

Aplicação

tert-Butylamine (t-butylamine) may be used in the synthesis of Zn₂-SnO₄ nanoparticles. It may be used to terminate the polymerization reaction during the synthesis of the following polymers (DAB =1,4-diaminobutane, BA=Boronic acid , PAA=functional poly(amido amine), ABOL=4-aminobutanol, Bn=Benzyl):

• (DAB-BA-PAA)
• (ABOL-BA-PAA)
• (DAB-Bn-PAA)

tert-Butylamine (TBA) is suitable for use as an indicator molecule in the study of NMR-based pH determination method, free of glass electrode errors in highly basic media. It is suitable for use in the synthesis of methyl β-ketophosphonate, titanium dioxide nanoparticles (TiO₂ NPs) and samarium oxide (Sm₂O₃) nanospheres and nanorods. It may be used in the following studies:

• As liquid hydrocarbon promoter in the systematic study on methane hydrate formation and dissociation.
• As an example in the study of the effect of amines in influencing atmospheric H₂SO₄-H₂O nucleation.
• Hydroamination of terminal alkynes.
• To measure the surface acidity of solid catalysts by temperature-programmed desorption.
• As a reductive nitrogen source in the atomic layer deposition technique used to deposit TaN thin films from TaCl₅ and TaBr₅.

Informações de segurança

• Pictogramas: GHS02,GHS06,GHS05
• Palavra indicadora: Danger
• Frases de perigo: H225,H302,H314,H331,H412
• Declarações de precaução: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): -36.4 °F - closed cup
• Ponto de fulgor (°C): -38 °C - closed cup
• Equipamento de proteção individual: Faceshields, Gloves, Goggles