309281

Iron(III) perchlorate hydrate

crystalline

• Sinônimo(s): Perchloric acid iron(III) salt hydrate
• Fórmula linear: Fe(ClO₄)₃ · xH₂O
• Número CAS: 15201-61-3
• Peso molecular: 354.20 (anhydrous basis)
• Número CE: 236-908-0
• Número MDL: MFCD00149705
• Código UNSPSC: 12352000
• ID de substância PubChem: 24858725
• NACRES: NA.22

Propriedades

• Formulário: crystalline
• Nível de qualidade: 100
• adequação da reação: reagent type: oxidant
• Impurezas: <0.10% chloride
• cor: yellow
• cadeia de caracteres SMILES: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• chave InChI: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Descrição

Aplicação

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Fulleroxazolidines
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Informações de segurança

• Pictogramas: GHS03,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H272,H315,H319,H335
• Declarações de precaução: P210 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 5.1A - Strongly oxidizing hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges