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Key Documents

252166

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine zinc

Sinônimo(s):

meso-Tetraphenylporphine, TPP, Zinc TPP

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About This Item

Fórmula empírica (Notação de Hill):
C44H28N4Zn
Número CAS:
Peso molecular:
678.11
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Nível de qualidade

λmax

418 nm

Desempenho do dispositivo OLED

ITO/TPD/Alq3:TPP (3%)/Alq3/Mg:Ag

  • Color: red
  • Max. Luminance: 42 V
  • Max. EQE: 0.07 %

cadeia de caracteres SMILES

[Zn]1n2c3ccc2c(-c4ccccc4)c5ccc(n5)c(-c6ccccc6)c7ccc(c(-c8ccccc8)c9ccc(n9)c3-c%10ccccc%10)n17

InChI

1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;

chave InChI

XPVVGUHKLPZAEN-DAJBKUBHSA-N

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Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


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Vijaykumar S Ijeri et al.
Langmuir : the ACS journal of surfaces and colloids, 24(3), 1070-1079 (2008-01-05)
Active spatial and temporal modulation of domains of singlet oxygen activity is demonstrated using electrochemical tools. Using singlet oxygen microscopy in photosensitized experiments, it is shown that singlet oxygen concentrations around an ultramicroelectrode can be controlled by applying a bias
Martin Kullmann et al.
Physical chemistry chemical physics : PCCP, 14(22), 8038-8050 (2012-05-03)
We report on a comprehensive transient absorption study with β,β'-linked bis[tetraphenylporphyrinato-zinc(II)] and its corresponding monomer, covering the ultrafast dynamics from femtoseconds up to several microseconds. By exciting these porphyrins either to their first (S(1)) or second (S(2)) electronically excited states
H Kolarova et al.
Toxicology in vitro : an international journal published in association with BIBRA, 19(7), 971-974 (2005-08-03)
The basis of photodynamic therapy (PDT) is the phototoxicity resulting from co-action of light, sensitizer and oxygen. In this study we demonstrate in vitro phototoxicity measurement on G361 cell lines using ZnTPPS(4) sensitizer bound to cyclodextrin hpbetaCD. We have proved
V L Schlegel et al.
Analytical chemistry, 63(3), 241-247 (1991-02-01)
The relationship between surface-enhanced resonance Raman scattering (SERRS) intensity and the rate of deposition during silver-island film preparation was examined, using zinc tetraphenylporphine (ZnTPP) as the adsorbate. The effect of the deposition rate on the optical properties of the films
Suyi Zhang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 88, 137-143 (2012-01-10)
The molecular interactions of 5,10,15,20-tetraphenylporphine zinc (ZnTPP) and 5,10,15,20-tetraphenyl-21H,23H-porphine cobalt(II) (CoTPP) with dimethyl methylphosphonate (DMMP) have been investigated by absorption/absorption difference spectroscopy. The interactions between the metalloporphyrins and DMMP change the absorbance characteristics of the porphyrins resulted from the formation

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