212911

Palladium hydroxide on carbon

extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

• Sinônimo(s): Pd(OH)₂/C, Pearlman’s catalyst
• Fórmula empírica (Notação de Hill): H₂O₂Pd
• Número CAS: 12135-22-7
• Peso molecular: 140.43
• Número CE: 235-219-2
• Número MDL: MFCD00064599
• Código UNSPSC: 12161600
• ID de substância PubChem: 24852754
• NACRES: NA.22

Propriedades

• forma: powder
• Nível de qualidade: 200
• contém: ≤50% water
• adequação da reação: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• Extensão da rotulagem: 20 wt. % loading (dry basis)
• matriz: carbon, wet support
• cadeia de caracteres SMILES: O[Pd]O
• InChI: 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
• chave InChI: NXJCBFBQEVOTOW-UHFFFAOYSA-L

Descrição

Aplicação

Addition of Pd/C to Pd(OH)₂/C improves the efficiency of N- or O-debenzylation.

Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.

Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)