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208248

Sigma-Aldrich

Aluminum acetylacetonate

98%

Sinônimo(s):

Al(acac)3, Aluminum 2,4-pentanedionate

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About This Item

Fórmula linear:
Al(C5H7O2)3
Número CAS:
Peso molecular:
324.31
Beilstein:
4157942
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

Ensaio

98%

Formulário

solid

adequação da reação

core: aluminum

p.e.

315 °C (lit.)

pf

190-193 °C (lit.)

cadeia de caracteres SMILES

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

chave InChI

KILURZWTCGSYRE-LNTINUHCSA-K

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Descrição geral

Alumunium acetylacetonate is insoluble in water but soluble in organic solvents. It reacts with alkalis, acids, water at elevated temperatures. It can be prepared by reacting AlCl3 and acetylacetonate.

Aplicação

Alumunium acetylacetonate may be used:
  • to prepare transparent superhydrophobic boehmite and silica films by sublimation,
  • to deposit alumunium oxide films by chemical vapor deposition,
  • as a catalyst.

Pictogramas

Skull and crossbones

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

244.4 °F

Ponto de fulgor (°C)

118 °C

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Os clientes também visualizaram

Aluminum oxide thin films prepared by chemical vapor deposition from aluminum acetylacetonate
Maruyama T, et al.
Applied Physics Letters, 60(3), 322-323 (1992)
Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate.
Nakajima A, et al.
Advanced Mat., 11(16), 1365-1368 (1999)
M Favarato et al.
Brain research, 569(2), 330-335 (1992-01-13)
To determine the influence of the metal coordination sphere on the permeability of the blood-brain barrier (BBB), rats were injected intraperitoneally with aluminum lactate (Al(lact)3), aluminum acetylacetonate (Al(acac)3), aluminum maltolate (Al(malt)3) at pH 7.5, or with physiological saline. Two h
Hans Riesen et al.
The journal of physical chemistry. A, 112(41), 10287-10293 (2008-09-16)
Site-selective and narrowed luminescence and excitation spectra in the region of the (2)E <-- (4)A 2 transitions are reported for single crystals of Al(acac) 3/Cr(III) and Al(3-Br-acac) 3/Cr(III) (where acac is acetylacetonate). The R 2 line is pronounced in the
S C Bondy et al.
Neuroscience letters, 267(1), 25-28 (1999-07-10)
The formation of the beta pleated configuration of the amyloid peptide fragment 25-35 in aqueous solution, has been studied using thioflavin-T fluorescence as an indicator of such folding. Both phosphate and adenosine triphosphate (ATP) enhance the formation of aggregated beta-sheets.

Artigos

The manufacture of monomers for use in ophthalmic applications is driven by the need for higher purity, improved reliability of manufacturing supply, but ultimately by the need for the increased comfort, convenience, and safety of contact lens wearers. Daily wear contact lenses have the potential to fill this need for many customers; however, their widespread use is constrained by higher costs compared to weekly- or monthly-based lenses. New approaches that improve cost structure and result in higher quality raw materials are needed to help make contact lenses more affordable and accelerate growth of the contact lens market.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

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