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Documentos Principais

140066

Sigma-Aldrich

1,3,5-Tribromobenzene

98%

Sinônimo(s):

1,3,5-Tribromobenzene

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About This Item

Fórmula empírica (Notação de Hill):
C6H3Br3
Número CAS:
Peso molecular:
314.80
Beilstein:
1858917
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

98%

Formulário

powder

p.e.

271 °C (lit.)

pf

117-121 °C (lit.)

grupo funcional

bromo

cadeia de caracteres SMILES

Brc1cc(Br)cc(Br)c1

InChI

1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H

chave InChI

YWDUZLFWHVQCHY-UHFFFAOYSA-N

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Descrição geral

  • 1,3,5-Tribromobenzene(TBB) acts as internal standard during derivatization step in determination of cyanide in human plasma and urine by gas chromatography-mass spectrometry.
  • TBB forms molecular complexes of 1:2 stoichiometry with [60]-and [70] fullerenes.
  • TBB reacts with perfluoroalkenylzinc reagent in the presence of Pd(Ph3)4 catalyst to yield a novel trifunctional monomer 1,3,5-tris(α, β, β-trifluorovinyl)benzene.

Frases de perigo

Classificações de perigo

Aquatic Chronic 4

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


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Guojie Liu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3054-3058 (2009-09-08)
Cyanide (CN) is a powerful poison and rapidly toxic agent. Because of its wide availability and high toxicity, quantification of CN in blood and urine is frequently required in clinical and forensic practice. We present a sensitive and less time
Lawrence A Ford et al.
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
Kakali Datta et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 66-70 (2005-11-01)
By UV-vis spectrophotometric method it has been shown that 1,3,5-tribromobenzene (TBB) forms molecular complexes of 1:2 stoichiometry with [60]- and [70]fullerenes. An isosbestic point could be detected in case of the [70]fullerene complex. The formation constant of the [60]fullerene complex
Y Suzuki et al.
Nucleic acids symposium series, (44)(44), 125-126 (2003-08-09)
We have designed a new type of a DNA dendrimer which has rigid branched structure. The branching molecule was prepared from 1,3,5-tribromobenzene. The dendrimer unit, in which three oligonucleotide-chains, two molecules of T15 and one molecule of A15, linked to
S Kage et al.
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.

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