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109835

Sigma-Aldrich

2-Methylpyridine

98%

Sinônimo(s):

2-Picoline, α-Picoline, 2-Methylpyridine, NSC 3409

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About This Item

Fórmula empírica (Notação de Hill):
C6H7N
Número CAS:
109-06-8
Peso molecular:
93.13
Beilstein:
104581
Número CE:
203-643-7
Número MDL:
MFCD00006332
Código UNSPSC:
12352100
ID de substância PubChem:
24846941
NACRES:
NA.22

densidade de vapor

3.2 (vs air)

pressão de vapor

10 mmHg ( 24.4 °C)

Ensaio

98%

temperatura de autoignição

995 °F

Lim. expl.

8.6 %

índice de refração

n20/D 1.500 (lit.)

p.e.

128-129 °C (lit.)

pf

−70 °C (lit.)

solubilidade

H2O: freely soluble
alcohol: miscible
diethyl ether: miscible

densidade

0.943 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

Cc1ccccn1

InChI

1S/C6H7N/c1-6-4-2-3-5-7-6/h2-5H,1H3

chave InChI

BSKHPKMHTQYZBB-UHFFFAOYSA-N

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Aplicação

2-Picoline (2-Methylpyridine) was used to study the electron and proton transfer reactions of lumiflavin using Fourier transform ion cyclotron resonance mass spectrometry.
2-Picoline was used in the synthetic pathway for the production of dearomatized, allylated and C-H bond activated pyridine derivatives.

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1C - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

84.2 °F - closed cup

Ponto de fulgor (°C)

29 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
STBJ3945
STBG7790
STBH3434
STBG5099V
STBF3380V

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2-Pyridinemethanol 98%

Sigma-Aldrich

P66602

2-Pyridinemethanol

J Christian Lennox et al.
The journal of physical chemistry. B, 121(46), 10530-10542 (2017-11-14)
A polypyridyl ruthenium complex with fluorinated bipyridine ligands and a covalently bound tyrosine moiety was synthesized, and its photo-induced proton-coupled electron transfer (PCET) reactivity in acetonitrile was investigated with transient absorption spectroscopy. Using flash-quench methodology with methyl viologen as an
Tianlan Zhang et al.
The journal of physical chemistry. A, 117(44), 11136-11141 (2013-09-07)
Examination of electron transfer and proton transfer reactions of lumiflavin and proton transfer reactions of the lumiflavin radical anion by Fourier transform ion cyclotron resonance mass spectrometry is described. From the equilibrium constant determined for electron transfer between 1,4-naphthoquinone and
Phillip Jochmann et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(43), 12115-12122 (2011-09-10)
A facile and general synthetic pathway for the production of dearomatized, allylated, and C-H bond activated pyridine derivatives is presented. Reaction of the corresponding derivative with the previously reported reagent bis(allyl)calcium, [Ca(C(3)H(5))(2)] (1), cleanly affords the product in high yield.
Malcolm E Tessensohn et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(16), 2250-2257 (2017-06-14)
The voltammetric behavior of 2,3,5,6-tetramethyl-1,4-phenylenediamine was found to be able to differentiate the hydrogen acceptor abilities of electroinactive pyridine compounds in acetonitrile. Weak and strong hydrogen acceptors were distinguished through the onset of a third oxidation process that came about
Nikolaos Kritikos et al.
Journal of chromatography. A, 1403, 70-80 (2015-06-06)
In the current study, quantitative structure-retention relationships (QSRR) were constructed based on data obtained by a LC-(ESI)-QTOF-MS/MS method for the determination of amino acid analogues, following their derivatization via chloroformate esters. Molecules were derivatized via n-propyl chloroformate/n-propanol mediated reaction. Derivatives
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Protocolos

US EPA Method 8270 (Appendix IX): GC Analysis of Semivolatiles on Equity®-5 (30 m x 0.25 mm I.D., 0.50 μm)

US EPA Method 8270 (Appendix IX): GC Analysis of Semivolatiles on Equity®-5 (30 m x 0.25 mm I.D., 0.50 μm)

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