398799

Dichlor(1,10-phenanthrolin)palladium(II)

• Empirische Formel (Hill-System): C₁₂H₈Cl₂N₂Pd
• CAS-Nummer: 14783-10-9
• Molekulargewicht: 357.53
• MDL-Nummer: MFCD00192008
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24864767
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES String: Cl[Pd]Cl.c1cnc2c(c1)ccc3cccnc23
• InChI: 1S/C12H8N2.2ClH.Pd/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2
• InChIKey: YGAISFRMWCCXCG-UHFFFAOYSA-L

Beschreibung

Anwendung

Catalyst for:

• Carbonylation of alkyl nitrites
• Arylation reactions
• Multiple acetylene insertions under Sonogashira reaction protocol
• Cross-coupling reactions of pyridine carboxylic acid chlorides with alkylzinc reagents
• Hydrophosphinylation of alkenes and alkynes
• Heck reaction
• Regioselective and stereoselective aminohalogenation reactions
• Reaction of chloroenynes and chlorodienes with Grignard reagents for the synthesis of stereodefined enynes and dienes

• Affects the aggregation of human prion protein PrP106-126

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable