225908

Allylmagnesiumchlorid -Lösung

2.0 M in THF

• Synonym(e): Allyl magnesium chloride, Allylchloromagnesium, Allylmagnesium chloride, Chloro-2-propen-1-ylmagnesium
• Lineare Formel: CH₂=CHCH₂MgCl
• CAS-Nummer: 2622-05-1
• Molekulargewicht: 100.83
• Beilstein: 3587316
• MDL-Nummer: MFCD00000473
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24853531
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 2.0 M in THF
• Dichte: 0.995 g/mL at 25 °C
• SMILES String: Cl[Mg]CC=C
• InChI: 1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
• InChIKey: PLYLAFITHJUEGX-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.

Anwendung

Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:

• Antipsychotic clopixol.
• Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
• 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H260,H314,H335,H336,H351
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• Zielorgane: Central nervous system, Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 1
• Flammpunkt (°F): 1.4 °F - closed cup - Solvent
• Flammpunkt (°C): -17 °C - closed cup - Solvent
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter