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324175

Sigma-Aldrich

Lithium 2-thienylcyanocuprate solution

0.25 M in THF

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About This Item

Empirical Formula (Hill Notation):
C5H3CuLiNS
CAS Number:
112426-02-5
Molecular Weight:
179.64
MDL number:
MFCD00013443
UNSPSC Code:
12352103
PubChem Substance ID:
24859429
NACRES:
NA.22

form

liquid

concentration

0.25 M in THF

density

0.895 g/mL at 25 °C

SMILES string

[Li]N=C=[Cu]c1cccs1

InChI

1S/C4H3S.CN.Cu.Li/c1-2-4-5-3-1;1-2;;/h1-3H;;;/q;-1;;+1

InChI key

BDZYNOMLDVYLHW-UHFFFAOYSA-N

General description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Application

Useful reagent for the preparation of higher-order cuprates.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL4605
SHBH2381V
SHBB5998
62296DJ
14615HH

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Aldrichimica Acta, 20, 58-58 (1987)

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Lipshutz Group – Professor Product Portal

Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.

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