940348

Dichloro(p-cymene)ruthenium(II) dimer ChemBeads

• Synonym(s): (p-Cymene)ruthenium(II) chloride dimer ChemBeads, Benzene-1-methyl-4-(1-methylethyl)-ruthenium complex ChemBeads
• Empirical Formula (Hill Notation): C₂₀H₂₈Cl₄Ru₂
• CAS Number: 52462-29-0
• Molecular Weight: 612.39
• UNSPSC Code: 12352100

Properties

• form: solid
• Quality Level: 100
• composition: , 4-6 wt. % (loading)
• reaction suitability: reagent type: catalyst
• SMILES string: [Cl-][Ru+2]123456([Cl-][Ru+2]789%10%11([Cl-])([Cl-]1)[CH]=%12[CH]%11=C%10(C(C)C)[CH]9=[CH]8C%127C)[CH]=%13[CH]6=C5(C(C)C)[CH]4=[CH]3C%132C
• InChI: InChI=1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4
• InChI key: LAXRNWSASWOFOT-UHFFFAOYSA-J

Description

General description

The ChemBeads product of the (p-Cymene)ruthenium(II) chloride dimer. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE).
Dichloro(p-cymene)ruthenium(II) dimer is commonly used as a ruthenium starting material, and has been used in:
- Bifunctional P-containing RuO2 catalysts prepared from surplus Ru coordination complexes applied to Zn/Air batteries.
- The synthesis of half-sandwich type platinum-group metal complexes of C-glucosaminyl azines.
- The C(sp2)-H bond functionalization along with concomitant (4+2) annulation of coumarin-3-carboxamide.
-The acceptor engineering of ruthenium metallocycles with high phototoxic indices for safer photodynamic therapy.

Features and Benefits

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable