206229

Ruthenium(III) chloride hydrate

ReagentPlus^®

• Synonym(s): Ruthenium trichloride
• Linear Formula: RuCl₃ · xH₂O
• CAS Number: 14898-67-0
• Molecular Weight: 207.43 (anhydrous basis)
• EC Number: 233-167-5
• MDL number: MFCD00149844
• PubChem Substance ID: 24852386
• NACRES: NA.23

Properties

• Quality Level: 200
• product line: ReagentPlus^®
• form: powder and chunks
• composition: Degree of hydration, ≤1 ; Ruthenium content, 40.00-49.00%
• reaction suitability: reagent type: catalyst; core: ruthenium
• impurities: ≤0.1% Insoluble matter (C=1%, 25% HCl)
• SMILES string: O.Cl[Ru](Cl)Cl
• InChI: 1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
• InChI key: BIXNGBXQRRXPLM-UHFFFAOYSA-K

Description

General description

soluble form

Application

It is used to prepare a nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation arylmethyl alcohols to the corresponding aldehydes. The product catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Ruthenium hydrated oxide, prepared from RhCl₃ when deposited on titania nanotubes can be used as a catalyt system for selective oxidation of alcohols by oxygen.

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Safety Information

• Pictograms: GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H302 - H314 - H411
• Precautionary Statements: P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
• Storage Class Code: 8A - Combustible, corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves