62118

Supelco

(R)-(+)-Limonene

analytical standard

Synonym(s):
(+)-Carvene, (+)-p-Mentha-1,8-diene, (R)-4-Isopropenyl-1-methyl-1-cyclohexene
Empirical Formula (Hill Notation):
C10H16
CAS Number:
Molecular Weight:
136.23
Beilstein/REAXYS Number:
2204754
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.24

Quality Level

grade

analytical standard

vapor density

4.7 (vs air)

vapor pressure

<3 mmHg ( 14.4 °C)

assay

≥99.0% (sum of enantiomers, GC)

form

neat

optical activity

[α]20/D +115.5±1°, c = 10% in ethanol

shelf life

limited shelf life, expiry date on the label

expl. lim.

6.1 %

application(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.473 (lit.)
n20/D 1.473

bp

176-177 °C (lit.)

density

0.842 g/mL at 20 °C (lit.)

Featured Industry

Agriculture
Cleaning Products
Cosmetics
Environmental
Flavors and Fragrances
Food and Beverages
Personal Care

format

neat

storage temp.

2-8°C

SMILES string

CC(=C)[C@@H]1CCC(C)=CC1

InChI

1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1

InChI key

XMGQYMWWDOXHJM-JTQLQIEISA-N

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General description

(R)-(+)-Limonene is a terpenoid compound that is abundantly present in many plants such as rosemary. It is highly associated with plant and insect interactions due to its tendency to attract insects.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Regioselective hydrogenation of the exocyclic double bond; Regioselective epoxidation of the endocyclic double bond

Signal Word

Danger

hazcat

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

storage_class_code

3 - Flammable liquids

WGK Germany

WGK 3

Flash Point(F)

123.8 °F - closed cup

Flash Point(C)

51 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

J.D. White et al.
Journal of the American Chemical Society, 103, 1813-1813 (1981)
R. Baker et al.
Journal of the Chemical Society. Chemical Communications, 414-414 (1987)
Whitefly attraction to rosemary (Rosmarinus officinialis L.) is associated with volatile composition and quantity
Sadeh D, et al.
PLoS ONE, 12(5) (2017)
T. Kitahara et al.
Tetrahedron, 43, 2689-2689 (1987)
Bharat B Aggarwal et al.
Biochemical pharmacology, 71(10), 1397-1421 (2006-03-28)
While fruits and vegetables are recommended for prevention of cancer and other diseases, their active ingredients (at the molecular level) and their mechanisms of action less well understood. Extensive research during the last half century has identified various molecular targets...
Protocols
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