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Key Documents

900397

Sigma-Aldrich

SnAP-ex 3-O-MOM P

95%

Synonym(s):

4-(Methoxymethoxy)-4-(tributylstannyl)butan-1-amine

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About This Item

Empirical Formula (Hill Notation):
C16H41NO2Sn
Molecular Weight:
398.21
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

form

paste

refractive index

n/D 1.4933

density

1.1407 g/mL

functional group

amine
ether

shipped in

wet ice

storage temp.

−20°C

Application

[SnAP reagents] provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the [Bode research group].

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3


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SnAP-eX reagents for the synthesis of exocyclic 3-amino-and 3-alkoxypyrrolidines and piperidines from aldehydes.
Luescher M U and Bode J W
Organic Letters, 18(11), 2652-2655 (2016)

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