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739324

Sigma-Aldrich

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)

greener alternative

1.1% in H2O, neutral pH, high-conductivity grade

Synonym(s):
Poly(2,3-dihydrothieno-1,4-dioxin)-poly(styrenesulfonate), PEDOT:PSS, Orgacon N-1005
MDL number:

Quality Level

grade

high-conductivity grade

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

concentration

1.1% in H2O

resistance

<100 Ω/sq, >70% visible light transmission (40 μm wet)

refractive index

n20/D 1.335

pH

5-7

viscosity

<100 cP(22 °C)

density

0.982 g/mL at 25 °C

greener alternative category

Enabling

storage temp.

2-8°C

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General description

Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is a conductive polymer that is formed by electropolymerizing 3,4-ethylenedioxythiophene in a solution of poly(styrenesulfonate) (PSS). PEDOT is doped with positive ions and PSS with negative ions. PEDOT:PSS is majorly used in organic electronics due to the properties such as:
  • low band gap
  • good optical properties
  • high conductivity
  • low redox potential
  • easy processing
  • tunable film forming ability

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Aqueous surfactant-free dispersion of PEDOT:PSS neutralized to pH >5. Suitable for preparation of pH-neutral transparent conductive films printed electronics applications (e.g. hole injection layers). A conducting polymer such as poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) anions (PEDOT/PSS) is widely used in various organic optoelectronic devices. PEDOT: PSS is a blend of cationic polythiopene derivative, doped with a polyanion. High electrical conductivity and good oxidation resistance of such polymers make it suitable for electromagnetic shielding and noise suppression. Thus, the polymer film was found to possess high transparency throughout the visible light spectrum and even into near IR and near UV regions, virtually 100% absorption from 900-2,000 nm. No absorption maximum from 400-800 nm. Impact of small electric and magnetic fields on the polymer was studied.

Application

PEDOT:PSS can be used as an electrode material that forms a layered structure with a high mobility for charge carriers. It can be used for a wide range of energy based applications, such as organic photovoltaics (OPVs), dye sensitized solar cells (DSSCs), organic light emitting diodes (OLEDs) and supercapacitors.
Virtually 100% absorption from 900-2,000 nm. No absorption maximum from 400-800 nm. Conductive polymer blend.

Packaging

100 g in poly bottle

Legal Information

Product of Agfa
Orgacon is a trademark of Agfa-Gevaert N.V.

Pictograms

CorrosionHealth hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Repr. 1B - Skin Irrit. 2

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

More Documents

Quotes and Ordering

Optimizing polymer tandem solar cells.
Jan Gilot et al.
Advanced materials (Deerfield Beach, Fla.), 22(8), E67-E71 (2010-03-11)
Roll-to-Roll Slot-Die Coated Organic Photovoltaic (OPV) Modules with High Geometrical Fill Factors
Galagan Y, et al.
Energy Technology, 3(8), 834-842 (2015)
Proton Electroinsertion in Self-Assembled Materials for Neutralization Pseudocapacitors
Facci T, et al.
Langmuir, 30(1), 426-431 (2013)
Metal salt modified PEDOT:PSS as anode buffer layer and its effect on power conversion efficiency of organic solar cells
Kadem B, et al.
Organic Electronics, 24, 73-79 (2015)
Screen-printable and flexible RuO2 nanoparticle-decorated PEDOT: PSS/graphene nanocomposite with enhanced electrical and electrochemical performances for high-capacity supercapacitor.
Cho S, et al.
ACS Applied Materials & Interfaces, 7(19), 10213-10227 (2015)

Articles

Conducting Polymer Materials for Flexible OPV Applications: Orgacon™ PEDOT : PSS

A detailed article on conducting polymer materials for flexible organic photovoltaics (OPVs) applications.

New Conducting and Semiconducting Polymers for Plastic Electronics

In the emerging field of organic printable electronics, such as OLEDs and organic photovoltaics (OPVs), there is a significant need for improved organic conducting and semiconducting materials. This paper reports our recent progress in two fields: 1) the development of solvent-based dispersions of the intrinsically conducting polymer (ICP) poly(3,4- ethylenedioxythiophene) (PEDOT) and 2) the synthesis of new electron-deficient (n-type) semiconducting polymers.

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