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Key Documents

683116

Sigma-Aldrich

Chiralyst P294

Umicore

Synonym(s):

(Acetylacetonato)(norbornadiene)rhodium(I), Acetylacetonatonorbornadienerhodium(I), Norbornadiene(acetylacetonato)rhodium, (Acetylacetonato)(bicyclo[2.2.1]hepta-2,5-diene)rhodium(I)

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About This Item

Empirical Formula (Hill Notation):
C12H15O2Rh
CAS Number:
Molecular Weight:
294.15
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

solid

reaction suitability

core: rhodium
reagent type: catalyst

mp

176-178 °C (lit.)

SMILES string

C1C2C=CC1C=C2.CC(=O)\C=C(\C)O[Rh]

InChI

1S/C7H8.C5H8O2.Rh/c1-2-7-4-3-6(1)5-7;1-4(6)3-5(2)7;/h1-4,6-7H,5H2;3,6H,1-2H3;/q;;+1/p-1/b;4-3-;

InChI key

IIQPRGKBFZGPIB-LWFKIUJUSA-M

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Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Articles

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

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