665029

1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium chloride

• Synonym(s): 1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride
• Empirical Formula (Hill Notation): C₂₂H₃₁ClN₂
• CAS Number: 639820-61-4
• Molecular Weight: 358.95
• MDL number: MFCD08276859
• UNSPSC Code: 12352005
• PubChem Substance ID: 24884707
• NACRES: NA.22

Properties

• form: solid
• reaction suitability: reagent type: catalyst; reaction type: Ring-Opening Polymerization
• mp: 263-280 °C
• SMILES string: [Cl-].Cc1cc(C)c(N2CC[N+](=C2)C34CC5CC(CC(C5)C3)C4)c(C)c1
• InChI: 1S/C22H31N2.ClH/c1-15-6-16(2)21(17(3)7-15)23-4-5-24(14-23)22-11-18-8-19(12-22)10-20(9-18)13-22;/h6-7,14,18-20H,4-5,8-13H2,1-3H3;1H/q+1;/p-1/t18-,19+,20-,22-;
• InChI key: MJOMRTQWLPXDJQ-ZFCGJYDVSA-M

Description

Application

Reactant for:

• Preparation of chelated ruthenium alkoxybenzylidene imidazolidene carbene pivalate catalysts for Z-selective olefin metathesis
• Use in ring-opening metathesis polymerization and ring-closing metathesis reactions via Grubbs catalyst mediated reactions
• Preparation of adamantyl-substituted N-heterocyclic carbene ligands in second-generation Grubbs-type iridium metathesis catalysis

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves