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470554

Sigma-Aldrich

[1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

97%

Synonym(s):

Ni(dppf)Cl2

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About This Item

Empirical Formula (Hill Notation):
C34H28Cl2FeNiP2
CAS Number:
67292-34-6
Molecular Weight:
683.98
MDL number:
MFCD00270284
UNSPSC Code:
12161600
PubChem Substance ID:
24870665
NACRES:
NA.22

Quality Level

100

assay

97%

form

solid

reaction suitability

core: nickel
reagent type: catalyst

mp

285 °C (dec.) (lit.)

SMILES string

[Fe].Cl[Ni]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2

InChI key

NSSWUOVWGSDARH-UHFFFAOYSA-L

Related Categories

pictograms

Health hazard
GHS08

signalword

Danger

Hazard Classifications

Carc. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN6415
MKCM0423
MKCC1842
MKBV7849V
MKBQ7870V

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Articles

Transition-Metal Catalysts

A variety of transition-metal catalysts for the Suzuki coupling reaction are now available in our catalog. The majority of these catalysts are palladium- and nickelbased, typically utilizing phosphine-derived ligands.

Nickel and Nickel-based Compounds (Complexes) as a Catalyst

Nickel transition metal and its complexes can be used as a catalyst in many synthetic transformations, like oxidative addition, C-H activation, reductive elimination, oxidative cyclization, oligomerization, and in cross-coupling reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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