All Photos(1)

432741

Sigma-Aldrich

(S)-(−)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde

95%

Synonym(s):
(−)-N-Boc-N,O-isopropylidene-L-serinal, tert-Butyl (S)-(−)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, Garner’s aldehyde
Empirical Formula (Hill Notation):
C11H19NO4
CAS Number:
Molecular Weight:
229.27
Beilstein:
3591324
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95%

optical activity

[α]20/D −90°, c = 1 in chloroform

refractive index

n20/D 1.445 (lit.)

bp

83-88 °C/1 mmHg (lit.)

density

1.06 g/mL at 25 °C (lit.)

SMILES string

[H]C(=O)[C@@H]1COC(C)(C)N1C(=O)OC(C)(C)C

InChI

1S/C11H19NO4/c1-10(2,3)16-9(14)12-8(6-13)7-15-11(12,4)5/h6,8H,7H2,1-5H3/t8-/m1/s1

InChI key

PNJXYVJNOCLJLJ-MRVPVSSYSA-N

Packaging

1 g in glass bottle

Application

Widely utilized in the asymmetric synthesis of natural products.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

226.4 °F - closed cup

Flash Point(C)

108 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Certificate of Origin

Guibourdenche, C. et al.
Tetrahedron Asymmetry, 4, 2041-2041 (1993)
Hoemann, M.Z. et al.
Tetrahedron Letters, 37, 953-953 (1996)
Roush, W.R. Hunt, J.A.
The Journal of Organic Chemistry, 60, 798-798 (1995)

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