282367

(1S,2S,3R,5S)-(+)-Pinanediol

99%

• Synonym(s): (+)-2-Hydroxyisopinocampheol, (1S,2S,3R,5S)-2,3-Pinanediol, (1S,2S,3R,5S)-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol, [1S-(1α,2α,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol
• Empirical Formula (Hill Notation): C₁₀H₁₈O₂
• CAS Number: 18680-27-8
• Molecular Weight: 170.25
• Beilstein/REAXYS Number: 1853591
• MDL number: MFCD00077851
• UNSPSC Code: 12352001
• PubChem Substance ID: 24857043
• NACRES: NA.22

Properties

• assay: 99%
• form: solid
• optical activity: [α]20/D +8.5°, c = 6.5 in toluene
• optical purity: ee: 99% (GLC)
• mp: 57-59 °C (lit.)
• SMILES string: CC1(C)C2C[C@@H](O)[C@@](C)(O)C1C2
• InChI: 1S/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8+,10-/m0/s1
• InChI key: MOILFCKRQFQVFS-OORONAJNSA-N

Description

Application

(1S,2S,3R,5S)-(+)-Pinanediol can be used as a chiral reagent in the synthesis of homochiral α-hydroxyketones and in the resolution of prolineboronate esters.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)