252670

Sigma-Aldrich

Chlorotriisopropoxytitanium(IV) solution

1.0 M in hexanes

Linear Formula:
[(CH3)2CHO]3TiCl
CAS Number:
Molecular Weight:
260.58
MDL number:
PubChem Substance ID:

form

solution

Quality Level

reaction suitability

core: titanium
reagent type: catalyst

concentration

1.0 M in hexanes

density

0.775 g/mL at 25 °C

SMILES string

CC(C)O[Ti](Cl)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.ClH.Ti/c3*1-3(2)4;;/h3*3H,1-2H3;1H;/q3*-1;;+4/p-1

InChI key

IFMWVBVPVXRZHE-UHFFFAOYSA-M

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Application

Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.

Packaging

100 mL in Sure/Seal™

Signal Word

Danger

Target Organs

Central nervous system

RIDADR

UN 2924 8(3) / PGII

WGK Germany

WGK 3

Flash Point(F)

71.6 °F

Flash Point(C)

22 °C

Certificate of Analysis

Certificate of Origin

Mesoporous Oxides and Their Applications to Hydrogen Storage
Hunt AJ, et al.
Material Matters, 4(2) null
The preparation and properties of some σ-alkyl and σ-aryl derivatives of titanium.
Rausch MD and Gordon HB
Journal of Organometallic Chemistry, 74(1), 85-90 (1974)
Stereoselective synthesis of 3, 7-diarylaminocholestanes by titanium-mediated reductive amination.
Ahmad Md Wasi and Kim HS
Steroids, 88, 53-59 (2014)
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