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Key Documents

202827

Sigma-Aldrich

Bismuth(III) oxide

powder, 99.999% trace metals basis

Synonym(s):

Dibismuth trioxide

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About This Item

Empirical Formula (Hill Notation):
Bi2O3
CAS Number:
Molecular Weight:
465.96
EC Number:
MDL number:
UNSPSC Code:
12352303
eCl@ss:
38080302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.999% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: bismuth

SMILES string

O=[Bi]O[Bi]=O

InChI

1S/2Bi.3O

InChI key

WMWLMWRWZQELOS-UHFFFAOYSA-N

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Application


  • Mass spectrometry standards: A significant advancement was made in developing an enantioselective high-performance liquid chromatography-tandem mass spectrometry method for the quantitative determination of methorphan and its O-demethylated metabolite, dextrorphan-d₃, in human blood, specifically for forensic applications in post-mortem samples. This method underscores the utility of stable isotope-labeled compounds like dextrorphan-d₃ in precise pharmacological research (Lo Faro et al., 2023).

Features and Benefits

Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, from V2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

Storage Class

11 - Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Arun Prakash Periasamy et al.
Talanta, 87, 15-23 (2011-11-22)
In this work, preparation and characterization of a novel nanocomposite containing bismuth oxide (Bi(2)O(3)) nanoparticles and multiwalled carbon nanotubes (MWCNTs) was presented. Powder X-ray diffraction (XRD) studies revealed that as-synthesized Bi(2)O(3) nanoparticles are crystalline and belong to α-phase with monoclinic
S Sanghi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 94-99 (2011-09-06)
Glasses with composition 20CdO·xBi(2)O(3)·(79.5-x)B(2)O(3) (15≤x≤35, x in mol%) containing 0.5 mol% of Er(3+) ions were prepared by melt-quench technique (1150°C in air). The amorphous nature of the glasses was confirmed by X-ray diffraction. The spectroscopic properties of the glasses were
Atsushi Satsuma et al.
Sensors (Basel, Switzerland), 11(2), 2155-2165 (2012-02-10)
Mixed potential sensors were fabriated using yttria-stabilized zirconia (YSZ) as a solid electrolyte and a mixture of Au and various metal oxides as a sensing electrode. The effects of calcination temperature ranging from 600 to 1,000 °C and acid-base properties
Lu You et al.
ACS nano, 6(6), 5388-5394 (2012-05-18)
The novel strain-driven morphotropic phase boundary (MPB) in highly strained BiFeO(3) thin films is characterized by well-ordered mixed phase nanodomains (MPNs). Through scanning probe microscopy and synchrotron X-ray diffraction, eight structural variants of the MPNs are identified. Detailed polarization configurations
Dirk Mansfeld et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(52), 14805-14810 (2011-11-29)
The reaction of [Bi(22)O(26)(OSiMe(2)tBu)(14)] (1) in THF with salicylic acid gave [Bi(22)O(24)(HSal)(14)] (2) first, which was converted into [Bi(38)O(45)(HSal)(22)(OH)(2)(DMSO)(16.5)]·DMSO·H(2)O (3·DMSO·H(2)O) after dissolution and crystallization from DMSO. Single-crystal X-ray diffraction analysis and ESI mass spectrometry associated with infrared multi-photon dissociation (IRMPD)

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