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155071

Sigma-Aldrich

Azidotrimethylsilane

95%

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Synonym(s):
Trimethylsilyl azide
Linear Formula:
(CH3)3SiN3
CAS Number:
4648-54-8
Molecular Weight:
115.21
Beilstein:
1903730
EC Number:
225-078-5
MDL number:
MFCD00001986
eCl@ss:
39100709
PubChem Substance ID:
24849336
NACRES:
NA.23

Quality Level

100

assay

95%

form

liquid

refractive index

n20/D 1.414 (lit.)

bp

52-53 °C/175 mmHg (lit.)

density

0.868 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)N=[N+]=[N-]

InChI

1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3

InChI key

SEDZOYHHAIAQIW-UHFFFAOYSA-N

Related Categories

Application

Versatile azidonation reagent for amines, amides, aldehydes, and ketones.

Packaging

10, 50 g in glass bottle

Pictograms

FlameSkull and crossbones
GHS02,GHS06

Signal Word

Danger

Hazard Statements

H225 - H301 + H311 + H331

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

42.8 °F - closed cup

Flash Point(C)

6 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

More Documents

FT-IR Condensed Phase
Pressure-Temperature Nomograph
Spectra - ATR-IR
Spectra for FT-IR Raman
Structure Search

Quotes and Ordering

Bulk Quote-Order Product
Journal of the American Chemical Society, 116, 4501-4501 (1994)
Journal of the American Chemical Society, 115, 9347-9347 (1993)
Well-defined poly (oxazoline)-b-poly (acrylate) amphiphilic copolymers: From synthesis by polymer-polymer coupling to self-organization in water
Guillerm, Brieuc, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 51(5), 1118-1128 (2013)
Covalent functionalization of epitaxial graphene by azidotrimethylsilane
Choi, Junghun, et al.
The Journal of Physical Chemistry C, 113(22), 9433-9435 (2009)
Azidotrimethylsilane
Li, B. L.
Synlett, 23(10), 1554-1555 (2012)
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Hydroazidation Catalyst

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Organic Azides and Azide Sources

Since the preparation of the first organic azide, phenyl azide, by Peter Griess in 1864 this energy-rich and versatile class of compounds has enjoyed considerable interest.

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