152854
4-Methoxybenzyloxycarbonyl azide
95%
Synonym(s):
4-Methoxybenzyl azidoformate
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About This Item
Linear Formula:
N3CO2CH2C6H4OCH3
CAS Number:
Molecular Weight:
207.19
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
95%
form
powder
reaction suitability
reaction type: click chemistry
mp
30-32 °C (lit.)
functional group
azide
storage temp.
2-8°C
SMILES string
COc1ccc(COC(=O)N=[N+]=[N-])cc1
InChI
1S/C9H9N3O3/c1-14-8-4-2-7(3-5-8)6-15-9(13)11-12-10/h2-5H,6H2,1H3
InChI key
NQBRFIXRZDTIRQ-UHFFFAOYSA-N
Application
4-Methoxybenzyloxycarbonyl azide was used to prepare N-4-methoxybenzyloxycarbonyl-L-α-aminoadipic acid.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Ox. Sol. 2
Storage Class
5.1B - Oxidizing hazardous materials
wgk_germany
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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J J Usher et al.
The Biochemical journal, 151(3), 729-739 (1975-12-01)
1. Phenoxymethylpenicillin sulphoxide 4-methoxybenzyl ester was labelled with 3H in its 2-beta-methyl group. Its specific radioactivity was 362 mCi/mmol. 2. Removal of the side chain of this compound yielded the corresponding ester of 6-aminopenicillanic acid sulphoxide and coupling of the
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